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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Norby, Poul
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (34/34 displayed)
- 2023Thin film and bulk morphology of PI-PS-PMMA miktoarm star terpolymers with both weakly and strongly segregated arm pairs
- 2023Time and space resolved operando synchrotron X-ray and Neutron diffraction study of NMC811/Si–Gr 5 Ah pouch cellscitations
- 2019Electrochemical stability of (La,Sr)CoO3-δ in (La,Sr)CoO3-δ/(Ce, Gd)O2-δ heterostructurescitations
- 2019Improved cycling stability in high-capacity Li-rich vanadium containing disordered rock salt oxyfluoride cathodescitations
- 2019Hydrothermal Synthesis, Characterization, and Sintering Behavior of Core-Shell Particles: A Principle Study on Lanthanum Strontium Cobaltite Coated with Nanosized Gadolinium Doped Ceriacitations
- 2019Hydrothermal Synthesis, Characterization, and Sintering Behavior of Core-Shell Particles: A Principle Study on Lanthanum Strontium Cobaltite Coated with Nanosized Gadolinium Doped Ceriacitations
- 2018Intercalation of lithium into disordered graphite in a working batterycitations
- 2018Hydrothermal Synthesis, Characterization, and Sintering Behavior of Core-Shell Particles: A Principle Study on Lanthanum Strontium Cobaltite Coated with Nanosized Gadolinium Doped Ceriacitations
- 2017Investigation of a Spinel-forming Cu-Mn Foam as an Oxygen Electrode Contact Material in a Solid Oxide Cell Single Repeating Unitcitations
- 2016Electron microscopy investigations of changes in morphology and conductivity of LiFePO4/C electrodescitations
- 2016Comprehensive analysis of TEM methods for LiFePO 4 /FePO 4 phase mapping: spectroscopic techniques (EFTEM, STEM-EELS) and STEM diffraction techniques (ACOM-TEM)citations
- 2016In situ X-ray powder diffraction studies of the synthesis of graphene oxide and formation of reduced graphene oxidecitations
- 2016Comprehensive analysis of TEM methods for LiFePO4/FePO4 phase mapping: spectroscopic techniques (EFTEM, STEM-EELS) and STEM diffraction techniques (ACOM-TEM)citations
- 2016Electron microscopy investigations of changes in morphology and conductivity of LiFePO 4 /C electrodescitations
- 2016Nanocomposite YSZ-NiO Particles with Tailored Structure Synthesized in a Two-Stage Continuous Hydrothermal Flow Reactor
- 2015In Situ Studies of Fe4+ Stability in β-Li3Fe2(PO4)3 Cathodes for Li Ion Batteriescitations
- 2015Size of oxide vacancies in fluorite and perovskite structured oxidescitations
- 2015In Situ High Resolution Synchrotron X-Ray Powder Diffraction Studies of Lithium Batteries
- 2015Capillary based Li-air batteries for in situ synchrotron X-ray powder diffraction studiescitations
- 2014Ionic conductivity and the formation of cubic CaH 2 in the LiBH 4 -Ca(BH 4 ) 2 compositecitations
- 2014Degradation Studies on LiFePO 4 cathode
- 2014Ionic conductivity and the formation of cubic CaH2 in the LiBH4-Ca(BH4)2 compositecitations
- 2014Degradation Studies on LiFePO4 cathode
- 2014In Situ Synchrotron XRD on a Capillary Li-O2 Battery Cell
- 2014Temperature- and Pressure-Induced Changes in the Crystal Structure of Sr(NH3)8Cl2citations
- 2013Structure and Magnetic Properties of Cu 3 Ni 2 SbO 6 and Cu 3 Co 2 SbO 6 Delafossites with Honeycomb Latticescitations
- 2013Structure and Magnetic Properties of Cu3Ni2SbO6 and Cu3Co2SbO6 Delafossites with Honeycomb Latticescitations
- 2013Capillary-based micro-battery cell for in situ X-ray powder diffraction studies of working batteries: a study of the initial intercalation and deintercalation of lithium into graphitecitations
- 2012Subsolidus phase relations of the SrO–WO3–CuO system at 800 °C in aircitations
- 2012Subsolidus phase relations of the SrO–WO 3 –CuO system at 800 °C in aircitations
- 2010Structural and microstructural changes during anion exchange of CoAl layered double hydroxides: an in situ X-ray powder diffraction studycitations
- 2009A Structural Study of Stacking Disorder in the Decomposition Oxide of MgAl Layered Double Hydroxide: A DIFFaX plus Analysiscitations
- 2009Conductivity and water uptake of Sr-4(Sr2Nb2)O-11 center dot nH(2)O and Sr-4(Sr2Ta2)O-11 center dot nH(2)Ocitations
- 2009Temperature dependant X-ray diffraction study of PrSr3Co1.5Fe1.5O10-d; n=3 Ruddlesden-Popper phasecitations
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article
A Structural Study of Stacking Disorder in the Decomposition Oxide of MgAl Layered Double Hydroxide: A DIFFaX plus Analysis
Abstract
The structure of the decomposition oxide of a nitrate-based magnesium-aluminum layered double hydroxide (LDH) was studied in detail by means of the DIFFaX+ refinement program. The DIFFaX+ refinement was based oil an in situ X-ray powder diffraction pattern (XRPD) collected at 890 degrees C and showed that the decomposition oxide is a disorder phase, where periclase-type layers and spinel-OT-type layers with different cation concentration and distribution are stacked along the direction corresponding to the cube diagonal of the ideal cubic periclase and/or spinel structure. The spinel-OT-type layers in the periclase-like decomposition phase are assumed to contain significant amounts of tetrahedrally coordinated aluminum atoms Furthermore, the DIFFaX+ refinement of the decomposition oxide indicated that the octahedra and tetrahedra of the spinel-OT-type layer and the octahedra of some of the periclase-type layer are distorted due to deviation in the cubic-close packing of the oxygen atoms in the decomposition oxide. Our detailed structural investigation described the disorder present in the periclase-like decomposition oxide and revealed the origin of an additional major diffraction peak tit the powder diffraction pattern which has up to now remained unexplained.