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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Domen, Kazunari
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Publications (7/7 displayed)
- 2020Plasma-enhanced chemical vapor deposition Ta<sub>3</sub>N<sub>5</sub> synthesis leading to high current density during PEC oxygen evolutioncitations
- 2018La5 Ti2 Cu0.9 Ag0.1 S5 O7 Modified with a Molecular Ni Catalyst for Photoelectrochemical H2 Generation.
- 2013La(M,Ti)(O,N) 3 (M = Zn, Ga) as visible light-driven photocatalyst for water splitting
- 2012A novel oxynitride photocatalyst system for water splitting : La 2 Zn 1-x Ti 1+x (O,N) 6
- 2010Oxynitrides Perovskites Thin Films : Photoelectrochemical Measurement Under Visible Light
- 2010Oxynitrides Perovskites Thin Films : Photoelectrochemical Measurement Under Visible Light
- 2009Photoelectrochemical Properties of Crystalline Perovskite Lanthanum Titanium Oxynitride Films under Visible Light.citations
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article
Photoelectrochemical Properties of Crystalline Perovskite Lanthanum Titanium Oxynitride Films under Visible Light.
Abstract
Thin films of the Lanthanum Titanium oxynitride perovskite (LaTiOxNy) synthesized by reactive radio-frequency sputtering on conductive Nb-doped Strontium Titanate (Nb:SrTiO3) substrates are evaluated as photoelectrodes for water splitting reaction under visible light. The films are characterized by x-ray diffraction analysis, energy-dispersive spectroscopy, scanning electron and atomic force microscopy, and ultraviolet-visible spectroscopy. Thin films with polycrystalline, oriented, or epitaxial structures are obtained depending on the substrate temperature and plasma composition. The band-gap energies of the films thus prepared are in the range 2.05 - 2.35 eV. Photoelectrochemical measurements reveal that the photoactivity of these films increases with the quality of film crystallization. The flat-band position of LaTiOxNy is found to change with pH of the reactant solution. Surface modification with colloidal IrO2 is also demonstrated to result in a marked increase in photoactivity, with the modified epitaxial LaTiOxNy film exhibiting a photocurrent density of ca. 70 A cm 2 at +1.0 V vs. Ag/AgCl at pH 4.5 in aqueous Na2SO4 solution under irradiation at visible wavelengths ( > 420 nm).