| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Vitillo, Jenny Grazia
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2018Understanding and Controlling the Dielectric Response of Metal–Organic Frameworkscitations
- 2018Time-resolved operando studies of carbon supported Pd nanoparticles under hydrogenation reactions by X-ray diffraction and absorptioncitations
- 2018On the structure of superbasic (MgO)n sites solvated in a faujasite zeolitecitations
- 2018Structure and Host–Guest Interactions of Perylene–Diimide Dyes in Zeolite L Nanochannelscitations
- 2017Core-Shell Structure of Palladium Hydride Nanoparticles Revealed by Combined X-ray Absorption Spectroscopy and X-ray Diffractioncitations
- 2014Evolution and reversibility of host/guest interactions with temperature changes in a methyl red@palygorskite polyfunctional hybrid nanocompositecitations
- 2012Evolution of host/guest interactions with heating in a palygorskite/methyl red (Maya Red) hybrid composite
- 2012Monolithic nanoporous-crystalline aerogels based on PPOcitations
- 2011Crystal structure refinement of a sepiolite/indigo Maya Blue pigment using molecular modelling and synchrotron diffractioncitations
- 2011Nanoporous crystalline phases of poly(2,6-dimethyl-1,4-phenylene)oxidecitations
- 2011Combined study of structural properties of metal-organic frameworks changing organic linkers and metal centers
- 2011Aerogels and polymorphism of isotactic poly(4-methyl-pentene-1)citations
- 2011Structure and thermodynamic properties of the NaMgH3 perovskitecitations
- 2011Structure-activity relationships of simple molecules adsorbed on MOF materials: in situ experiments vs. theory
- 2010Hydrogen adsorption by δ and ε crystalline phases of syndiotactic polystyrene aerogelscitations
- 2010Storage of hydrogen as a guest of a nanoporous polymeric crystalline phasecitations
- 2010Hydrogen adsorption by delta and epsilon crystalline phases of syndiotactic polystirene aerogelscitations
- 2009CO adsorption on CPO-27-Ni coordination polymer: spectroscopic features and interaction energycitations
- 2009CO adsorption on cpo-27-ni coordination polymercitations
- 2008Oriented TiO2 nanostructured pillar arrayscitations
- 2008Local structure of CPO-27-Ni metallorganic framework upon dehydration and coordination of NOcitations
Places of action
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article
CO adsorption on cpo-27-ni coordination polymer
Abstract
<p>The microporous metal-organic framework Ni<sub>2</sub>(dhtp) (H <sub>4</sub>dhtp ) 2,5-dihydroxyterephtalic acid) is a 3D network that maintains crystallinity and porosity after solvent removal. A mild thermal treatment in high vacuo at 393 K removes completely water allowing to obtain a MOF material with honeycomb structure able to strongly coordinate CO at room temperature. In this contribution, the reactivity toward CO of CPO-27-Ni has been studied by the combined use of infrared, extended X-ray absorption fine structure, X-ray absorption near edge structure, and UV-vis spectropies and microcalorimetry. Most of the Ni<sup>2+</sup> sites are involved in the interaction (about 80%), forming 1:1 linear adducts whose interaction enthalpy is slightly above 50 kJ/mol. In the presence of CO, a large modification of the vibrational and electronic properties of the material with respect to the dehydrated one has been observed.</p>