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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Rajh, T.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2010Effect of calcination temperature on the photocatalytic reduction and oxidation processes of hydrothermally synthesized titania nanotubes.citations
- 2008The important role of tetrahedral Ti{sup 4+} sites in the phase transformation and photocatalytic activity of TiO{sub 2} nanocomposites.citations
- 2008The role of surface/interfacial Cu{sup 2+} sites in the photocatalytic activity of coupled CuO-TiO{sub 2} nanocomposites.citations
- 2008Synthesizing mixed-phase TiO{sub 2} nanocomposites using a hydrothermal method for photooxidation and photoreduction applications.citations
- 2003Biology of TiO{sub 2}-oligonucleotide nanocomposites.citations
- 2002Intracellular localization of titanium dioxide-biomolecule nanocomposites.citations
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article
The role of surface/interfacial Cu{sup 2+} sites in the photocatalytic activity of coupled CuO-TiO{sub 2} nanocomposites.
Abstract
Coupled CuO-TiO{sub 2} nanocomposite photocatalysts were prepared by a deposition precipitation method and were characterized with a variety of techniques. Electron paramagnetic resonance (EPR) spectroscopy was employed to study the local structures of surface/interfacial Cu{sup 2+}+ sites using Cu{sup 2+} as a sensitive paramagnetic probe. The addition of bulk CuO to TiO{sub 2} led to decreased photocatalytic efficiency in the degradation of methylene blue. However, doping with a very small amount of CuO (0.1 wt % copper loading) significantly enhanced the photocatalytic activity of TiO{sub 2}. EPR study of the TiO{sub 2} surface revealed the presence of both highly dispersed CuO clusters and substitutional Cu{sup 2+} sites (Ti-O-Cu linkages) at 0.1 wt % copper loading. The data suggest that the Ti-O-Cu linkages contributed to the improved photooxidative activity of the 0.1% CuO-TiO{sub 2} nanocomposite. In contrast, at higher loadings the bulk form of CuO created charge recombination centers lowering the photoactivity of the composites.