Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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Materials Map under construction

The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (1/1 displayed)

  • 2015Cation Depth-Distribution at Alkali Halide Aqueous Solution Surfaces41citations

Places of action

Chart of shared publication
Silly, Mathieu G.
1 / 11 shared
Gallet, Jean-Jacques
1 / 8 shared
Rochet, François
1 / 6 shared
Bournel, Fabrice
1 / 11 shared
Sirotti, Fausto
1 / 18 shared
Tissot, Héloïse
1 / 4 shared
Chart of publication period
2015

Co-Authors (by relevance)

  • Silly, Mathieu G.
  • Gallet, Jean-Jacques
  • Rochet, François
  • Bournel, Fabrice
  • Sirotti, Fausto
  • Tissot, Héloïse
OrganizationsLocationPeople

article

Cation Depth-Distribution at Alkali Halide Aqueous Solution Surfaces

  • Silly, Mathieu G.
  • Gallet, Jean-Jacques
  • Oivieri, Giorgia
  • Rochet, François
  • Bournel, Fabrice
  • Sirotti, Fausto
  • Tissot, Héloïse
Abstract

Using synchrotron radiation Near-Ambient Pressure X-ray photoemission spectroscopy (NAP-XPS) in surface and bulk sensitive conditions, we specifically explored the depth distribution of Na+ ions near the vapor/liquid interface of saturated solutions of sodium halides (NaCl, NaBr, and NaI) kept at 278 K under a pressure of 8 mbar. By varying the photoelectron kinetic energy, and hence the probing depth, we show that the Na+ depth distribution near the surface is highly sensitive to the size and polarizability of the anion. The large polarizable anions, Br– and I– that segregate at the surface, tend to drag the Na+ ions closer to the liquid–water surface. However, this situation is not observed for the NaCl solution, in line with recent theoretical results.

Topics
  • impedance spectroscopy
  • surface
  • x-ray photoelectron spectroscopy
  • Sodium