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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Liu, Yu
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (41/41 displayed)
- 2024Enhancing the Performance of SiC-based Varistors through the Use of SPS Processing and Fluxes
- 2024Solution-processed, surface-engineered, polycrystalline CdSe-SnSe exhibiting low thermal conductivitycitations
- 2023Epitaxially Driven Phase Selectivity of Sn in Hybrid Quantum Nanowirescitations
- 2023Epitaxially Driven Phase Selectivity of Sn in Hybrid Quantum Nanowirescitations
- 2023Enhanced Thermoelectric Performance of Tin(II) Sulfide Thin Films Prepared by Aerosol Assisted Chemical Vapor Depositioncitations
- 2022Surface functionalization of surfactant-free particles : a strategy to tailor the properties of nanocomposites for enhanced thermoelectric performancecitations
- 2022Surface functionalization of surfactant-free particles: A strategy to tailor the properties of nanocomposites for enhanced thermoelectric performancecitations
- 2022Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performancecitations
- 2022Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performancecitations
- 2022Fluctuating Ru trimer precursor to a two-stage electronic transition in RuPcitations
- 2021Exploiting the lability of metal halide perovskites for doping semiconductor nanocompositescitations
- 2021Exploiting the lability of metal halide perovskites for doping semiconductor nanocompositescitations
- 2020Valence band electronic structure of the van der Waals ferromagnetic insulators: VI3 and CrI3citations
- 2020Influence of the ligand stripping on the transport properties of nanoparticle-based PbSe nanomaterialscitations
- 2020Coherent Epitaxial Semiconductor-Ferromagnetic Insulator InAs/EuS Interfacescitations
- 2020Coherent Epitaxial Semiconductor–Ferromagnetic Insulator InAs/EuS Interfaces: Band Alignment and Magnetic Structurecitations
- 2020Bismuth telluride–copper telluride nanocomposites from heterostructured building blockscitations
- 2019Ligand-mediated band engineering in bottom-up assembled SnTe nanocomposites for thermoelectric energy conversioncitations
- 2019Ligand-mediated band engineering in bottom-up assembled SnTe nanocomposites for thermoelectric energy conversioncitations
- 2019Tuning transport properties in thermoelectric nanocomposites through inorganic ligands and heterostructured building blockscitations
- 2019Tuning transport properties in thermoelectric nanocomposites through inorganic ligands and heterostructured building blockscitations
- 2019Tuning transport properties in thermoelectric nanocomposites through inorganic ligands and heterostructured building blockscitations
- 2019Enhanced hetero-junction quality and performance of kesterite solar cells by aluminum hydroxide nanolayers and efficiency limitation revealed by atomic-resolution scanning transmission electron microscopycitations
- 2019Enhanced hetero‐junction quality and performance of kesterite solar cells by aluminum hydroxide nanolayers and efficiency limitation revealed by atomic‐resolution scanning transmission electron microscopycitations
- 2018Field effect enhancement in buffered quantum nanowire networkscitations
- 2018Crystallographically textured nanomaterials produced from the liquid phase sintering of Bi x Sb 2– x Te 3 nanocrystal building blockscitations
- 2018High thermoelectric performance in crystallographically textured n-type Bi 2 Te 3– x Se x produced from asymmetric colloidal nanocrystalscitations
- 2018Crystallographically textured nanomaterials produced from the liquid phase sintering of BixSb₂-xTe₃ nanocrystal building blockscitations
- 2018High Thermoelectric Performance in Crystallographically Textured n-Type Bi2Te3- xSex Produced from Asymmetric Colloidal Nanocrystalscitations
- 2017Solution-based synthesis and processing of Sn- and Bi-doped Cu₃SbSe₄ nanocrystals, nanomaterials and ring-shaped thermoelectric generatorscitations
- 2017Bottom-up engineering of thermoelectric nanomaterials and devices from solution-processed nanoparticle building blockscitations
- 2017Solution-based synthesis and processing of Sn- and Bi-doped Cu3SbSe4 nanocrystals, nanomaterials and ring-shaped thermoelectric generatorscitations
- 2017Superconducting order from disorder in 2H-TaSe2−xSxcitations
- 2017Solution-based synthesis and processing of Sn- and Bi-doped Cu 3 SbSe 4 nanocrystals, nanomaterials and ring-shaped thermoelectric generatorscitations
- 2016Thermoelectric properties of semiconductor-metal composites produced by particle blendingcitations
- 2016Thermoelectric properties of semiconductor-metal composites produced by particle blendingcitations
- 2016Colloidal AgSbSe 2 nanocrystals: surface analysis, electronic doping and processing into thermoelectric nanomaterialscitations
- 2016High-performance thermoelectric nanocomposites from nanocrystal building blockscitations
- 2016High-performance thermoelectric nanocomposites from nanocrystal building blockscitations
- 2014Magnetic Iron Oxide Nanoparticles: Reproducible Tuning of the Size and Nanosized-Dependent Composition, Defects, and Spin Cantingcitations
- 2014Tuning of Synthesis Conditions by Thermal Decomposition toward Core–Shell Co x Fe 1– x O@Co y Fe 3– y O 4 and CoFe 2 O 4 Nanoparticles with Spherical and Cubic Shapescitations
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article
Magnetic Iron Oxide Nanoparticles: Reproducible Tuning of the Size and Nanosized-Dependent Composition, Defects, and Spin Canting
Abstract
Équipe 401 : Nanomatériaux pour la vie et développement durable ; International audience ; Iron oxide nanoparticles (NPs) with average sizes in the range 4-28 nm have been obtained by varying different synthesis parameters of the thermal decomposition of an iron precursor (iron stearate) in the presence of surfactants in high boiling solvents. The synthesis parameters affect the NPs nucleation and growth steps, by modifying the stability of iron stearate on which depend the monomer formation and concentration, in agreement with the LaMer model. The monomer formation, which is reaction time and/or temperature dependent, is thus found to vary mainly as a function of the nature of solvents and ligands. The structural and magnetic characterizations of NPs with sizes in the range 5-20 nm confirm that the composition of NPs evolves from the maghemite for small sizes (typically <8 nm) up to a core of rather stoichiometric magnetite surrounded by an oxidized shell for large sizes (>12 nm) via a perturbed oxidized state for intermediate sizes. The values of saturation magnetization lower than those of bulk magnetite and maghemite were found to be related to this composition evolution and to the presence of oxidation defects, surface spin canting and volume spin canting as a function of NPs diameter. Small NPs presented mainly a surface spin canting. NPs with large sizes display M-s which depends on their oxidized shell thickness, defects and surface spin canting. NPs with intermediate sizes display a surface and in particular a volume spin canting due to a disordered structure induced by a perturbed oxidation state in these NPs.