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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Tenhu, Heikki
University of Helsinki
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (35/35 displayed)
- 2024Clay Composites by In Situ Polymerization of Ionic Liquid-Based Dispersions
- 2023Clay Composites by In Situ Polymerization of Ionic Liquid-Based Dispersions
- 2022Well-dispersed clay in photopolymerized poly(ionic liquid) matrixcitations
- 2020Poly(N,N-dimethylaminoethyl methacrylate) for removing chromium (VI) through polymer-enhanced ultrafiltration techniquecitations
- 2018Poly(N,N-dimethylaminoethyl methacrylate) for removing chromium (VI) through polymer-enhanced ultrafiltration techniquecitations
- 2017Water-Dispersible Silica-Polyelectrolyte Nanocomposites Prepared via Acid-Triggered Polycondensation of Silicic Acid and Directed by Polycationscitations
- 2016Rheological properties of thermoresponsive nanocomposite hydrogelscitations
- 2016AuNP-Polymeric Ionic Liquid Composite Multicatalytic Nanoreactors for One-Pot Cascade Reactionscitations
- 2016Water-dispersible silica-polyelectrolyte nanocomposites prepared via acid-triggered polycondensation of silicic acid and directed by polycations.citations
- 2016Water-Dispersible Silica-Polyelectrolyte Nanocomposites Prepared via Acid-Triggered Polycondensation of Silicic Acid and Directed by Polycationscitations
- 2016AuNP−polymeric ionic liquid composite multicatalytic nanoreactors for one-pot cascade reactionscitations
- 2013pH dependent polymer surfactants for hindering BSA adsorption to oil-water interface
- 2013Thermoresponsiveness of PDMAEMA. Electrostatic and stereochemical effectscitations
- 2013Imidazolium-Based Poly(ionic liquid)s as New Alternatives for CO2 Capture.citations
- 2012Polymer-Modulated Optical Properties of Gold Solscitations
- 2012Polymer-Modulated Optical Properties of Gold Solscitations
- 2012IR-sintering of ink-jet printed metal-nanoparticles on papercitations
- 2012Screening of the effect of biocidal agents released from poly (acrylic acid) matrices on mould growthcitations
- 2012Crystal morphology modification by the addition of tailor-made stereocontrolled poly(N-isopropyl acrylamide)citations
- 2011Characterization of Water-Dispersible n-Type Poly(benzimidazobenzophenanthroline) Derivatives.citations
- 2009Poly(ethylene imine) and Tetraethylenepentamine as Protecting Agents for Metallic Copper Nanoparticlescitations
- 2009Grafting of montmorillonite nano-clay with butyl acrylate and methyl methacrylate by atom transfer radical polymerization: Blends with poly(BuA-co-MMA).citations
- 2009Tuning the structure of thermosensitive gold nanoparticle monolayerscitations
- 2009Rheological properties of associative star polymers in aqueous solutionscitations
- 2009Grafting of montmorillonite nano-clay with butyl acrylate and methyl methacrylate by atom transfer radical polymerizationcitations
- 2009Rheological Properties of Associative Star Polymers in Aqueous Solutions: Effect of Hydrophobe Length and Polymer Topologycitations
- 2009Association behavior and properties of copolymers of perfluorooctyl ethyl methacrylate and eicosanyl methacrylatecitations
- 2008Direct Imaging of Nanoscopic Plastic Deformation below Bulk Tg and Chain Stretching in Temperature-Responsive Block Copolymer Hydrogels by Cryo-TEMcitations
- 2007Metallic nanoparticles in a polymeric matrix
- 2007Metallic nanoparticles in a polymeric matrix:Electrical impedance switching and negative differential resistance
- 2007Phase behavior and temperature-responsive molecular filters based on self-assembly of polystyrene-block-poly(N-isopropylacrylamide)-block-polystyrenecitations
- 2006A New method for measuring free drug concentrationcitations
- 2005Physical Properties of Aqueous Solutions of a Thermo-Responsive Neutral Copolymer and an Anionic Surfactantcitations
- 2005Association in Aqueous Solutions of a Thermoresponsive PVCL-g-C11EO42 Copolymer.citations
- 2004Complexation of DNA with Poly(methacryl oxyethyl trimethylammonium chloride) and Its Poly(oxyethylene) Grafted Analogue.citations
Places of action
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article
Polymer-Modulated Optical Properties of Gold Sols
Abstract
The optical properties of Au nanoparticles (D ≈ 2.3-8 nm) grafted with a stabilizing polymer with a wide range of chain lengths (Mw ≈ 6.5K-29.5K) were studied quant. in different dielec. solvents.Mie-Drude dipolar theory was applied to model the localized surface plasmon resonance (SPR) peak position, as well as the peak width of the absorption spectra, using the dielec. function of Au.The modeled spectra yielded information on the dielec. function of the polymer shell, εs, from which the av. polymer concn. in the shell was deduced.Combining information from optical modeling and structural properties obtained from small-angle neutron scattering (SANS) on the polymer shell thickness and from TEM on the Au core size, the SPR peak shifts and their attenuated sensitivity to solvent refractive index were characterized.The SPR behaviors for all of the Au colloids with different core sizes and graft chain lengths were thus expressed as a function of the effective polymer vol. fraction, p, of the composite nanoparticle.Sensitivity to the solvent dielec. property decreased until, for p > 0.9 (corresponding to an effective shell thickness on the order of the core radius), the SPR mode was frozen in by the polymer shell and lost sensitivity to the solvent. [on SciFinder(R)]