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De, D. M. Leeuw
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Publications (4/4 displayed)
- 2014Relation between the electroforming voltage in alkali halide-polymer diodes and the bandgap of the alkali halidecitations
- 2012Role of hole injection in electroforming of LiF-polymer memory diodescitations
- 2010Trapping of electrons in metal oxide-polymer memory diodes in the initial stage of electroformingcitations
- 2009Poly(diketopyrrolopyrrole-terthiophene) for ambipolar logic and photovoltaicscitations
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article
Role of hole injection in electroforming of LiF-polymer memory diodes
Abstract
Al/LiF/poly(spirofluorene)/Ba/Al diodes submitted to bias voltages near 15 V undergo a change to a nonvolatile memory known as electroforming. Prior to electroforming, electron trapping occurs, followed by a tunneling current due to electrons from the polymer into LiF. At the onset voltage for electroforming, a sudden electroluminescence burst originating from electronic excitations in the polymer is detected. This confirms that hole injection into the polymer through LiF occurs leading to nonvolatile resistive switching.