| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Lammertink, Rob
University of Twente
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2024Streamer formation dynamics with mixed bacterial species: effects of cultivation conditions, hydrodynamics, and speciescitations
- 2024Mismatch and mix
- 2022Comparative assessment of hydrocarbon separation performance of bulky poly(urethane-urea)s toward rubbery membranescitations
- 2020Elucidating the effect of chain extenders substituted by aliphatic side chains on morphology and gas separation of polyurethanescitations
- 2019Association of hard segments in gas separation through polyurethane membranes with aromatic bulky chain extenderscitations
- 2017Fabrication of nanoporous graphene/polymer composite membranescitations
- 2015Controlled formation of anatase and rutile TiO2 thin films by reactive magnetron sputteringcitations
- 2015Intrinsic Photocatalytic Assessment of Reactively Sputtered TiO2 Filmscitations
- 2011Hollow fiber ultrafiltration membranes with microstructured inner skincitations
- 2011Carbon nanofibers in catalytic membrane microreactorscitations
- 2010Microstructured hollow fibers for ultrafiltrationcitations
- 2010Shrinkage effects during polmer phase separation on microfabricated moldscitations
- 2010Surface texturing inside ceramic macro/micro channelscitations
- 2010Polymeric microsieves via phase separation microfabricationcitations
- 2009Microcontact Printing of Dendrimers, Proteins, and Nanoparticles by Porous Stampscitations
- 2009Micropatterned polymer films by vapor-induced phase separation using permeable moldscitations
- 2007Morphology and Microtopology of Cation-Exchange Polymers and the Origin of the Overlimiting Currentcitations
- 2006Polymeric microsieves produced by phase separation micromoldingcitations
- 2006Superhydrophobic Surfaces Having Two-Fold Adjustable Roughness Prepared in a Single Stepcitations
- 2005New replication technique for the fabrication of thin polymeric microfluidic devices with tunable porositycitations
- 2005Electrochemistry of Surface-Grafted Stimulus-Responsive Monolayers of Poly(ferrocenyldimethylsilane) on Goldcitations
Places of action
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article
Morphology and Microtopology of Cation-Exchange Polymers and the Origin of the Overlimiting Current
Abstract
In electrodialysis desalination processes, the operating current density is limited by concentration polarization. In contrast to other membrane processes such as ultrafiltration, in electrodialysis, current transport above the limiting current is possible. In this work, the origin of the overlimiting current at cation-exchange polymers is investigated. We show that, under certain experimental conditions, electroconvection is the origin of the overlimiting conductance. The theory concerning electroconvection predicts a shortening of the plateau length of membranes with increased conductive or geometrical heterogeneity. We investigate the influence of these two parameters and show that the creation of line undulations on the membrane surface normal to the flow direction, having distances in the range of approximately 50−200% of the boundary-layer thickness, lead to an earlier onset of the overlimiting current. The plateau length of the undulated membranes is reduced by up to 60% compared to that of a flat membrane. These results verify the existence of electroconvection as a mechanism destabilizing the laminar boundary layer at the liquid−membrane interface and causing ionic transport above the limiting current density.