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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sambi, Mauro
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2011Interplay between Layer-Resolved Chemical Composition and Electronic Structure in a Sn/Pt(110) Surface Alloycitations
- 2005A LEED I-V structural determination of the c(4x2) Ni3O4/Pd(100) monolayer phase: an ordered array of Ni vacanciescitations
- 2005Growth and thermal behaviour of NiO nanolayers on Pd(100)citations
- 2005Ultrathin TiO<i><sub>x</sub></i> Films on Pt(111): A LEED, XPS, and STM Investigationcitations
- 2004The growth of ultrathin films of vanadium oxide on TiO2(110)citations
- 2003Growth of NiO ultrathin films on Pd(100) by post-oxidation of Ni films: the effect of pre-adsorbed oxygencitations
- 2000An X-ray photoelectron diffraction structural characterisation of epitaxial ultrathin RuO2/TiO2(110) films obtained by decomposition of Ru3(CO)12citations
- 2000An XPD structural characterisation of epitaxial ultrathin RuO2/TiO2 (110) films obtained by decomposition of Ru3(CO)12citations
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article
Ultrathin TiO<i><sub>x</sub></i> Films on Pt(111): A LEED, XPS, and STM Investigation
Abstract
Ultrathin ordered titanium oxide films on Pt(111) surface are prepared by reactive evaporation of Ti in oxygen. By varying the Ti dose and the annealing conditions (i.e., temperature and oxygen pressure), six different long-range ordered phases are obtained. They are characterized by means of low-energy electron diffraction (LEED), X-ray photoemission spectroscopy (XPS), and scanning tunneling microscopy (STM). By careful optimization of the preparative parameters, we find conditions where predominantly single phases of TiOx, revealing distinct LEED pattern and STM images, are produced. XPS binding energy and photoelectron diffraction (XPD) data indicate that all the phases, except one (the stoichiometric rect-TiO2), are one monolayer thick and composed of a Ti−O bilayer with interfacial Ti. Atomically resolved STM images confirm that these TiOx phases wet the Pt surface, in contrast to rect-TiO2. This indicates their interface stabilization. At a low Ti dose (0.4 monolayer equivalents, MLE), an incommens...