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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zalewska, Aldona
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Publications (8/8 displayed)
- 2023The Influence of Ionizing Radiation on Paclitaxel-Loaded Nanoparticles Based on PLGAcitations
- 2016Understanding of Lithium 4,5-Dicyanoimidazolate-Poly(ethylene oxide) System: Influence of the Architecture of the Solid Phase on the Conductivitycitations
- 2010Detailed studies on the fillers modification and their influence on composite, poly(oxyethylene)-based polymeric electrolytescitations
- 2007Structure, transport properties and interfacial stability of PVdF/HFP electrolytes containing modified inorganic fillercitations
- 2006Physico- and electrochemistry of composite electrolytes based on PEODME–LiTFSI with TiO2citations
- 2004Effect of cation and salt concentration on conductivity and microstructure characteristics of polyether electrolytes doped with alkali metal perchloratescitations
- 2003New poly(acrylamide) based (polymer in salt) electrolytes: preparation and spectroscopic characterizationcitations
- 2000Effect of filler surface group on ionic interactions in PEG−LiClO4−Al2O3 composite polyether electrolytescitations
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article
Effect of cation and salt concentration on conductivity and microstructure characteristics of polyether electrolytes doped with alkali metal perchlorates
Abstract
The effect of the type of alkali metal cation on the conductivity and ion transport mechanism is analyzed for PEGME−MClO4 electrolytes (where M = Li, Na, K, Rb, Cs). The data are obtained in the wide alkali metal perchlorate concentration (from 10-5 to 5 mol/kg PEGME) range. The obtained results evidenced that at salt concentrations less than 10-3 mol/kg higher conductivities are obtained for Li, Na, and K perchlorates, whereas at salt concentrations greater than 1 mol/kg conductivities measured for Cs and Rb perchlorates are higher. At intermediate salt concentration ranges, conductivities measured for all systems are similar. The observed trends are supported by the viscosity and IR results describing the ion−ion and ion−polymer interactions. The formation of ionic associates is additionally monitored by the application of the Fuoss−Kraus formalism to the salt concentration dependence of the molar conductivity.