Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (1/1 displayed)

  • 2001Experimental and quantum study of adsorption of ozone (O-3) on amorphous water ice film40citations

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Borget, Fabien
1 / 2 shared
Chiavassa, Thierry
1 / 2 shared
Allouche, Alain
1 / 1 shared
Chart of publication period
2001

Co-Authors (by relevance)

  • Borget, Fabien
  • Chiavassa, Thierry
  • Allouche, Alain
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article

Experimental and quantum study of adsorption of ozone (O-3) on amorphous water ice film

  • Borget, Fabien
  • Chiavassa, Thierry
  • Aycard, Jean-Pierre
  • Allouche, Alain
Abstract

Ozone (O-3) adsorption and desorption on amorphous water ice film is monitored by Fourier transform infrared spectroscopy (FTIR) using the temperature-programmed desorption (TPD) method. A single type of site is observed between O-3 and ice which involves the dangling OH bonds of the amorphous ice. The O-3 desorption occurs between 70 and 90 K and the associated desorption energy is 20 KJ/mol. This value is in good agreement with that estimated from Periodic Hartree-Fock (PHF) calculations using a density functional theory (DFT) evaluation of the electronic correlation energy. These calculations confirmed the electrostatic nature of the interaction forces. The dangling OH vibrational frequency shift is also calculated and is close to the 60 cm(-1) experimental value. A small amount of ozone is incorporated into the bulk and desorbs at the onset of the ice crystallization near 145 K.

Topics
  • density
  • impedance spectroscopy
  • amorphous
  • theory
  • density functional theory
  • Fourier transform infrared spectroscopy
  • crystallization