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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Braga, Mh
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2021Direct growth of MoS2 on electrolytic substrate and realization of high-mobility transistorscitations
- 2021Structural Batteries: A Reviewcitations
- 2021An All-Solid-State Coaxial Structural Battery Using Sodium-Based Electrolytecitations
- 2020Performance of a ferroelectric glass electrolyte in a self-charging electrochemical cell with negative capacitance and resistancecitations
- 2020Experimental and ab initio study of the Ag-Li system for energy storage and high-temperature solderscitations
- 2018Formation enthalpy of Ga-Li intermetallic phases. Experiment vs. calculationscitations
- 2018Extraordinary Dielectric Properties at Heterojunctions of Amorphous Ferroelectricscitations
- 2017Electric Dipoles and Ionic Conductivity in a Na+ Glass Electrolytecitations
- 2017First principles, thermal stability and thermodynamic assessment of the binary Ni-W systemcitations
- 2017Alternative strategy for a safe rechargeable batterycitations
- 2015Theoretical investigation of defect structure in B2 TrSc (Tr=Cd, Ru) alloyscitations
- 2014Li-Si phase diagram: Enthalpy of mixing, thermodynamic stability, and coherent assessmentcitations
- 2014Optimization and assessment of the Ag-Ca phase diagramcitations
- 2013Experimental and First Principles Study of the Ni-Ti-W Systemcitations
- 2012Study of the Cu-Li-Mg-H system by thermal analysiscitations
- 2010Neutron powder diffraction and first-principles computational studies of CuLixMg2-x (x congruent to 0.08), CuMg2, and Cu2Mgcitations
- 2007THE BEHAVIOUR OF THE LATTICE PARAMETERS IN THE Bi-Sn-Zn SYSTEMcitations
- 2000The Cu-Li-Mg system at room temperaturecitations
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article
Extraordinary Dielectric Properties at Heterojunctions of Amorphous Ferroelectrics
Abstract
Materials having a high dielectric constant are needed for a variety of electrical applications from transistors to capacitors. Ferroelectric amorphous-oxide (glass) alkali-ion electrolytes of composition A(2.99)Ba(0.005)ClO (A = Li, Na) are shown by two different types of measurement and different consistent analyses to have extraordinarily high dielectric constants, varying from 10(9) at 25 degrees C to 10(10) at 220 degrees C if the glass is properly conditioned. These anomalously high dielectric properties coexist with alkali-ion conductivities at 25 degrees C that are equivalent to those of the best organic-liquid electrolytes of a Li-ion cell, and cyclic voltammetry (CV) in a Au/glass electrolyte/Au cell is stable from -10 to +10 V. A model to interpret microscopically all the key features of the CV curves shows that the electric-double-layer capacitors that form at the gold/electrolyte interfaces in the Au/glass electrolyte/Au heterojunction reverse polarization at an applied voltage V = +/- 2.1 V, resulting in three almost equivalent discharging capacitances for a single physical capacitor from -10 to +10 V.