| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Boyer, Cyrille
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024Microphase Separation 3D Printing of Binary Inorganic Polymer Precursors to Prepare Nanostructured Carbon‐Ceramic Multimaterialscitations
- 2024Design and 3D Printing of Polyacrylonitrile‐Derived Nanostructured Carbon Architecturescitations
- 2023Microphase Separation 3D Printing of Binary Inorganic Polymer Precursors to Prepare Nanostructured Carbon‐Ceramic Multimaterialscitations
- 2023Exploiting NIR light mediated Surface-Initiated PhotoRAFT polymerization for orthogonal control polymer brushes and facile post-modification of complex architecture through opaque barrierscitations
- 2022Soft Liquid Metal Infused Conductive Spongescitations
- 2022P003 Synthetic antifungal peptide mimic kills <i>Candida albicans</i> by targeting protein glycosylation and synergistically prevents infection
- 2021Incorporation and antimicrobial activity of nisin Z within carrageenan/chitosan multilayerscitations
- 2018Discrete and Stereospecific Oligomers Prepared by Sequential and Alternating Single Unit Monomer Insertioncitations
- 2011High-order multiblock copolymers via iterative Cu(0)-mediated radical polymerizations (SET-LRP): Toward biological precisioncitations
- 2010Telechelic Diiodopoly(VDF-co-PMVE) Copolymers by Iodine Transfer Copolymerization of Vinylidene Fluoride (VDF) with Perfluoromethyl vinyl ether (PMVE)citations
- 2010Synthesis of hollow polymer nanocapsules exploiting gold nanoparticles as sacrificial templatescitations
- 2009Iodine Transfer Copolymerization of Vinylidene Fluoride and a-Trifluoromethacrylic Acid in Emulsion Process Without Any Surfactantscitations
- 2008Radical Terpolymerization of 1,1,2-Trifluoro-2-pentafluorosulfanylethylene and Pentafluorosulfanylethylene in the Presence of Vinylidene Fluoride and Hexafluoropropylene by Iodine Transfer Polymerizationcitations
- 2008Synthesis of triblock copolymers from glycolysed poly(ethylene terephthalate) by living radical polymerizationcitations
- 2007Synthesis and Characterisation of Organogels from ABA Triblock Copolymerscitations
- 2007Synthesis and Characterisation of Organogels from ABA Triblock Copolymerscitations
- 2006Kinetics of the iodine transfer polymerization of vinylidene fluoridecitations
- 2006Reverse Iodine Transfer Polymerization (RITP) of Methyl Methacrylatecitations
- 2006Poly(vinylidene fluoride)-b-poly(styrene) Block Copolymers by Iodine Transfer Polymerization (ITP): Synthesis, Characterization, and Kinetics of ITPcitations
- 2005Iodine Transfer Polymerization (ITP) of Vinylidene Fluoride (VDF). Influence of the Defect of VDF Chaining on the Control of ITPcitations
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article
Discrete and Stereospecific Oligomers Prepared by Sequential and Alternating Single Unit Monomer Insertion
Abstract
<p>Natural biopolymers, such as DNA and proteins, have uniform microstructures with defined molecular weight, precise monomer sequence, and stereoregularity along the polymer main chain that affords them unique biological functions. To reproduce such structurally perfect polymers and understand the mechanism of specific functions through chemical approaches, researchers have proposed using synthetic polymers as an alternative due to their broad chemical diversity and relatively simple manipulation. Herein, we report a new methodology to prepare sequence-controlled and stereospecific oligomers using alternating radical chain growth and sequential photoinduced RAFT single unit monomer insertion (photo-RAFT SUMI). Two families of cyclic monomers, the indenes and the N-substituted maleimides, can be alternatively inserted into RAFT agents, one unit at a time, allowing the monomer sequence to be controlled through sequential and alternating monomer addition. Importantly, the stereochemistry of cyclic monomer insertion into the RAFT agents is found to be trans-selective along the main chains due to steric hindrance from the repeating monomer units. All investigated cyclic monomers provide such trans-selectivity, but analogous acyclic monomers give a mixed cis- and trans-insertion.</p>