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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mkami, Hassane El
University of St Andrews
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (3/3 displayed)
- 2018Distance measurement of a noncovalently bound Y@C82 Pair with double electron electron resonance spectroscopycitations
- 2008Multifrequency EPR analysis of the positive polaron in I2-doped poly(3-hexylthiophene) and in poly[2-methoxy-5-(3,7-dimethyloctyloxy)]-1,4- phenylenevinylenecitations
- 2007Transition metal- And rare earth-doped ZnOcitations
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article
Distance measurement of a noncovalently bound Y@C82 Pair with double electron electron resonance spectroscopy
Abstract
Paramagnetic endohedral fullerenes with long spin coherence times, such as N@C<sub>60</sub> and Y@C<sub>82</sub>, are being explored as potential spin quantum bits (qubits). Their use for quantum information processing requires a ways to hold them in fixed spatial arrangements. Here we report the synthesis of a porphyrin-based two-site receptor <b>1</b>, offering a rigid structure that binds spin-active fullerenes (Y@C<sub>82</sub>) at a center-to-center distance of 5.0 nm, predicted from molecular simulations. The spin-spin dipolar coupling was measured with the pulsed EPR spectroscopy technique of double electron electron resonance (DEER) and analysed to give a distance of 4.87 nm with a small distribution of distances.