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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Gagliardi, Laura
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2021Tuning the Conductivity of Hexa-Zirconium(IV) Metal-Organic Frameworks by Encapsulating Heterofullerenescitations
- 2020Insights into the structure−activity relationships in metal−Organic framework-supported nickel catalysts for ethylene hydrogenationcitations
- 2020Isomerization and Selective Hydrogenation of Propynecitations
- 2019Lead-Free Double Perovskites Cs 2 InCuCl 6 and (CH 3 NH 3 ) 2 InCuCl 6 : Electronic, Optical, and Electrical Propertiescitations
- 2018Beyond the Active Sitecitations
- 2018Computational Study of Structural and Electronic Properties of Lead-Free CsMI3 Perovskites (M = Ge, Sn, Pb, Mg, Ca, Sr, and Ba)citations
- 2018Catalytic descriptors and electronic properties of single-site catalysts for ethene dimerization to 1-butenecitations
- 2017Bridging Zirconia Nodes within a Metal-Organic Framework via Catalytic Ni-Hydroxo Clusters to Form Heterobimetallic Nanowirescitations
- 2017Metal-Organic Framework Supported Cobalt Catalysts for the Oxidative Dehydrogenation of Propane at Low Temperaturecitations
- 2017Methane Oxidation to Methanol Catalyzed by Cu-Oxo Clusters Stabilized in NU-1000 Metal-Organic Frameworkcitations
- 2017Atomic Layer Deposition in a Metal-Organic Frameworkcitations
- 2016Sintering-Resistant Single-Site Nickel Catalyst Supported by Metal-Organic Frameworkcitations
- 2016Computationally Guided Discovery of a Catalytic Cobalt-Decorated Metal-Organic Framework for Ethylene Dimerizationcitations
- 2015Targeted Single-Site MOF Node Modificationcitations
- 2012Volatilities of actinide and lanthanide N, N -dimethylaminodiboranate chemical vapor deposition precursorscitations
- 2006The characterization of molecular alkaly metal azidescitations
Places of action
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article
Methane Oxidation to Methanol Catalyzed by Cu-Oxo Clusters Stabilized in NU-1000 Metal-Organic Framework
Abstract
<p>Copper oxide clusters synthesized via atomic layer deposition on the nodes of the metal-organic framework (MOF) NU-1000 are active for oxidation of methane to methanol under mild reaction conditions. Analysis of chemical reactivity, in situ X-ray absorption spectroscopy, and density functional theory calculations are used to determine structure/activity relations in the Cu-NU-1000 catalytic system. The Cu-loaded MOF contained Cu-oxo clusters of a few Cu atoms. The Cu was present under ambient conditions as a mixture of ∼15% Cu<sup>+</sup> and ∼85% Cu<sup>2+</sup>. The oxidation of methane on Cu-NU-1000 was accompanied by the reduction of 9% of the Cu in the catalyst from Cu<sup>2+</sup> to Cu<sup>+</sup>. The products, methanol, dimethyl ether, and CO<sub>2</sub>, were desorbed with the passage of 10% water/He at 135 °C, giving a carbon selectivity for methane to methanol of 45-60%. Cu oxo clusters stabilized in NU-1000 provide an active, first generation MOF-based, selective methane oxidation catalyst.</p>