| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Castillo-Blas, Celia
University of Cambridge
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Synthetic and analytical considerations for the preparation of amorphous metal-organic frameworks.
- 2024Transient intermediate in the formation of an amorphous metal-organic framework.
- 2024Structural insights into hybrid immiscible blends of metal-organic framework and sodium ultraphosphate glasses
- 2024Transient intermediate in the formation of an amorphous metal-organic frameworkcitations
- 2024Mechanochemically-induced glass formation from two-dimensional hybrid organic-inorganic perovskites.
- 2024Mechanochemically-induced glass formation from two-dimensional hybrid organic–inorganic perovskitescitations
- 2024Mechanochemically-induced glass formation from two-dimensional hybrid organic–inorganic perovskitescitations
- 2023Interfacial Bonding between a Crystalline Metal-Organic Framework and an Inorganic Glasscitations
- 2023Structural insights into hybrid immiscible blends of metal-organic framework and sodium ultraphosphate glasses.
- 2023Interfacial Bonding between a Crystalline Metal-Organic Framework and an Inorganic Glass.
- 2023Structural insights into hybrid immiscible blends of metal–organic framework and sodium ultraphosphate glassescitations
- 2022Principles of melting in hybrid organic-inorganic perovskite and polymorphic ABX3 structures.
- 2022Materials Formed by Combining Inorganic Glasses and Metal-Organic Frameworks.
- 2020The role of defects in the properties of functional coordination polymerscitations
- 2020Unravelling the local structure of catalytic Fe-oxo clusters stabilized on the MOF-808 metal organic-frameworkcitations
- 2016Crystal phase competition by addition of a second metal cation in solid solution metal–organic frameworkscitations
Places of action
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article
Interfacial Bonding between a Crystalline Metal-Organic Framework and an Inorganic Glass
Abstract
<p>The interface within a composite is critically important for the chemical and physical properties of these materials. However, experimental structural studies of the interfacial regions within metal-organic framework (MOF) composites are extremely challenging. Here, we provide the first example of a new MOF composite family, i.e., using an inorganic glass matrix host in place of the commonly used organic polymers. Crucially, we also decipher atom-atom interactions at the interface. In particular, we dispersed a zeolitic imidazolate framework (ZIF-8) within a phosphate glass matrix and identified interactions at the interface using several different analysis methods of pair distribution function and multinuclear multidimensional magic angle spinning nuclear magnetic resonance spectroscopy. These demonstrated glass-ZIF atom-atom correlations. Additionally, carbon dioxide uptake and stability tests were also performed to check the increment of the surface area and the stability and durability of the material in different media. This opens up possibilities for creating new composites that include the intrinsic chemical properties of the constituent MOFs and inorganic glasses.</p>