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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sajzew, Roman
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Observation of a Reversible Order‐Order Transition in a Metal‐Organic Framework – Ionic Liquid Nanocomposite Phase‐Change Materialcitations
- 2024Structural insights into hybrid immiscible blends of metal-organic framework and sodium ultraphosphate glasses
- 2024Gas‐Separating Metal‐Organic Framework Membrane Films on Large‐Area 3D‐Printed Tubular Ceramic Scaffoldscitations
- 2023Surface Hardness and Abrasion Threshold of Chemically Strengthened Soda-Lime Silicate Glasses After Steam Processing
- 2023Interfacial Bonding between a Crystalline Metal-Organic Framework and an Inorganic Glasscitations
- 2023Precise control over gas-transporting channels in zeolitic imidazolate framework glassescitations
- 2023Structural insights into hybrid immiscible blends of metal-organic framework and sodium ultraphosphate glasses.
- 2023Gas Separating Metal-Organic Framework Membrane Films on Large Area 3D-Printed Tubular Ceramic Scaffolds
- 2023Fabrication and characterization of SiO2 glass containing YbPO4 crystalscitations
- 2023Interfacial Bonding between a Crystalline Metal-Organic Framework and an Inorganic Glass.
- 2023Structural insights into hybrid immiscible blends of metal–organic framework and sodium ultraphosphate glassescitations
- 2023Controlled formation of gold nanoparticles with tunable plasmonic properties in tellurite glasscitations
- 2023Research data supporting 'Structural insights into hybrid immiscible blends of metal-organic framework and sodium ultraphosphate glasses'
- 2022Mechanoluminescence from highly transparent ZGO:Cr spinel glass ceramicscitations
- 2022Advancing the mechanical performance of glasses: Perspectives and challengescitations
- 2021Thermal strengthening of low‐expansion glasses and thin‐walled glass products by ultra‐fast heat extractioncitations
Places of action
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article
Interfacial Bonding between a Crystalline Metal-Organic Framework and an Inorganic Glass
Abstract
<p>The interface within a composite is critically important for the chemical and physical properties of these materials. However, experimental structural studies of the interfacial regions within metal-organic framework (MOF) composites are extremely challenging. Here, we provide the first example of a new MOF composite family, i.e., using an inorganic glass matrix host in place of the commonly used organic polymers. Crucially, we also decipher atom-atom interactions at the interface. In particular, we dispersed a zeolitic imidazolate framework (ZIF-8) within a phosphate glass matrix and identified interactions at the interface using several different analysis methods of pair distribution function and multinuclear multidimensional magic angle spinning nuclear magnetic resonance spectroscopy. These demonstrated glass-ZIF atom-atom correlations. Additionally, carbon dioxide uptake and stability tests were also performed to check the increment of the surface area and the stability and durability of the material in different media. This opens up possibilities for creating new composites that include the intrinsic chemical properties of the constituent MOFs and inorganic glasses.</p>