| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Blanc, Frédéric
University of Liverpool
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Superionic lithium transport via multiple coordination environments defined by two-anion packingcitations
- 2023Interfacial Bonding between a Crystalline Metal-Organic Framework and an Inorganic Glasscitations
- 2023Off-the-Shelf Gd(NO 3 ) 3 as an Efficient High-Spin Metal Ion Polarizing Agent for Magic Angle Spinning Dynamic Nuclear Polarizationcitations
- 2023Interfacial Bonding between a Crystalline Metal-Organic Framework and an Inorganic Glass.
- 2021Melting of hybrid organic–inorganic perovskitescitations
- 2021Melting of hybrid organic-inorganic perovskites.
- 201817 O solid-state NMR spectroscopy of A 2 B 2 O 7 oxides:quantitative isotopic enrichment and spectral acquisition?citations
- 201817O solid-state NMR spectroscopy of A2B2O7 oxidescitations
- 2016A comparison of the amorphization of zeolitic imidazolate frameworks (ZIFs) and aluminosilicate zeolites by ball-millingcitations
Places of action
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article
Interfacial Bonding between a Crystalline Metal-Organic Framework and an Inorganic Glass
Abstract
<p>The interface within a composite is critically important for the chemical and physical properties of these materials. However, experimental structural studies of the interfacial regions within metal-organic framework (MOF) composites are extremely challenging. Here, we provide the first example of a new MOF composite family, i.e., using an inorganic glass matrix host in place of the commonly used organic polymers. Crucially, we also decipher atom-atom interactions at the interface. In particular, we dispersed a zeolitic imidazolate framework (ZIF-8) within a phosphate glass matrix and identified interactions at the interface using several different analysis methods of pair distribution function and multinuclear multidimensional magic angle spinning nuclear magnetic resonance spectroscopy. These demonstrated glass-ZIF atom-atom correlations. Additionally, carbon dioxide uptake and stability tests were also performed to check the increment of the surface area and the stability and durability of the material in different media. This opens up possibilities for creating new composites that include the intrinsic chemical properties of the constituent MOFs and inorganic glasses.</p>