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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bahri, Mounib
University of Liverpool
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024Phase-selective recovery and regeneration of end-of-life electric vehicle blended cathodes via selective leaching and direct recyclingcitations
- 2024Radiation Effects in Uranium Nitride and Zirconium Nitride
- 2024Superionic lithium transport via multiple coordination environments defined by two-anion packingcitations
- 2023Phase-selective recovery and regeneration of end-of-life electric vehicle blended cathodes via selective leaching and direct recyclingcitations
- 2022MOF-Derived Multi-heterostructured Composites for Enhanced Photocatalytic Hydrogen Evolution: Deciphering the Roles of Different Componentscitations
- 2022A Pyrene-4,5,9,10-Tetraone-Based Covalent Organic Framework Delivers High Specific Capacity as a Li-Ion Positive Electrodecitations
- 2021An in situ investigation of the thermal decomposition of metal-organic framework NH2-MIL-125 (Ti)citations
- 2020Zinc-blende group III-V/group IV epitaxy: Importance of the miscutcitations
- 2020Phase selective synthesis of nickel silicide nanocrystals in molten salts for electrocatalysis of the oxygen evolution reactioncitations
- 2019Bimetallic Phosphide (Ni,Cu) 2 P Nanoparticles by Inward Phosphorus Migration and Outward Copper Migrationcitations
- 2019Bimetallic Phosphide (Ni,Cu) 2 P Nanoparticles by Inward Phosphorus Migration and Outward Copper Migrationcitations
- 2019Kinked silicon nanowires: Superstructures by metal assisted chemical etchingcitations
- 2019Kinked Silicon Nanowires: Superstructures by Metal-Assisted Chemical Etchingcitations
- 2019Bringing Conducting Polymers to High Order: Toward Conductivities beyond 10 5 S cm −1 and Thermoelectric Power Factors of 2 mW m −1 K −2citations
- 2016Thermal Management of Monolithic Versus Heterogeneous Lasers Integrated on Siliconcitations
- 2015Quantitative evaluation of microtwins and antiphase defects in GaP/Sinanolayers for a III–V photonics platform on siliconusing a laboratory Xray diffraction setupcitations
- 2015Quantitative evaluation of microtwins and antiphase defects in GaP/Sinanolayers for a III–V photonics platform on siliconusing a laboratory Xray diffraction setupcitations
Places of action
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article
A Pyrene-4,5,9,10-Tetraone-Based Covalent Organic Framework Delivers High Specific Capacity as a Li-Ion Positive Electrode
Abstract
<p>Electrochemically active covalent organic frameworks (COFs) are promising electrode materials for Li-ion batteries. However, improving the specific capacities of COF-based electrodes requires materials with increased conductivity and a higher concentration of redox-active groups. Here, we designed a series of pyrene-4,5,9,10-tetraone COF (PT-COF) and carbon nanotube (CNT) composites (denoted as PT-COFX, whereX = 10, 30, and 50 wt % of CNT) to address these challenges. Among the composites, PT-COF50 achieved a capacity of up to 280 mAh g<sup>-1</sup> as normalized to the active COF material at a current density of 200 mA g<sup>-1</sup>, which is the highest capacity reported for a COF-based composite cathode electrode to date. Furthermore, PT-COF50 exhibited excellent rate performance, delivering a capacity of 229 mAh g<sup>-1</sup> at 5000 mA g<sup>-1</sup> (18.5C). Usingoperando Raman microscopy the reversible transformation of the redox-active carbonyl groups of PT-COF was determined, which rationalizes an overall 4 e<sup>-</sup>/4 Li<sup>+</sup> redox process per pyrene-4,5,9,10-tetraone unit, accounting for its superior performance as a Li-ion battery electrode. </p>