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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Suturina, Elizaveta A.
University of Bath
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2022Toward Opto-Structural Correlation to Investigate Luminescence Thermometry in an Organometallic Eu(II) Complexcitations
- 2020Metal-organic magnets with large coercivity and ordering temperatures up to 242°Ccitations
- 2018Spin state in perfluorinated FePc films on Cu(111) and Ag(111) in dependence on film thicknesscitations
- 2017Spin dynamics of light-induced charge separation in composites of semiconducting polymers and PC60BM revealed using Q-band pulse EPRcitations
- 2013Bis(toluene)chromium(I) [1,2,5]Thiadiazolo[3,4-c ][1,2,5]thiadiazolidyl and [1,2,5]Thiadiazolo[3,4-b ]pyrazinidylcitations
- 2010Heterospin π-heterocyclic radical-anion saltcitations
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article
Toward Opto-Structural Correlation to Investigate Luminescence Thermometry in an Organometallic Eu(II) Complex
Abstract
<p>Lanthanide-based luminescent materials have unique properties and are well-studied for many potential applications. In particular, the characteristic 5d → 4f emission of divalent lanthanide ions such as Eu<sup>II</sup> allows for tunability of the emissive properties via modulation of the coordination environment. We report the synthesis and photoluminescence investigation of pentamethylcyclopentadienyleuropium(II) tetrahydroborate bis(tetrahydrofuran) dimer (1), the first example of an organometallic, discrete molecular Eu<sup>II</sup> band-shift luminescence thermometer. Complex 1 exhibits an absolute sensitivity of 8.2 cm<sup>–1</sup> K<sup>–1</sup> at 320 K, the highest thus far observed for a lanthanide-based band-shift thermometer. Opto-structural correlation via variable-temperature single-crystal X-ray diffraction and fluorescence spectroscopy allows rationalization of the remarkable thermometric luminescence of complex 1 and reveals the significant potential of molecular Eu<sup>II</sup> compounds in luminescence thermometry.</p>