693.932 PEOPLE
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| Naji, M. |
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| Azevedo, Nuno Monteiro |
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Lambai, Aloshious
VTT Technical Research Centre of Finland
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024In-situ SEM micropillar compression and nanoindentation testing of SU-8 polymer up to 1000 s−1 strain ratecitations
- 2024Correlated high throughput nanoindentation mapping and microstructural characterization of wire and arc additively manufactured 2205 duplex stainless steelcitations
- 2023Effect of stiff substrates on enhancing the fracture resistance of Barium Titanate thin filmscitations
- 2023Evolution of alumina phase structure in thermal plasma processingcitations
- 2023Evolution of alumina phase structure in thermal plasma processingcitations
- 2022Effect of Welding Direction and Bead Pattern in Alloy 52 / SA508 Repair Weld
- 2022Multistage Reversible Tg Photomodulation and Hardening of Hydrazone-Containing Polymerscitations
- 2021Multistage Reversible Tg Photomodulation and Hardening of Hydrazone-Containing Polymerscitations
- 2020A52M/SA52 Dissimilar Metal RPV Repair Weld: Experimental Evaluation and Post-Weld Characterizationscitations
- 2020A52M/SA52 Dissimilar Metal RPV Repair Weld:Experimental Evaluation and Post-Weld Characterizationscitations
- 2020A52M/SA52 Dissimilar Metal RPV Repair Weld : Experimental Evaluation and Post-Weld Characterizationscitations
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article
Multistage Reversible Tg Photomodulation and Hardening of Hydrazone-Containing Polymers
Abstract
<p>The glass transition temperature (Tg) of a series of polyacrylate- and polymethacrylate-based polymers having bistable hydrazone photoswitches as pendants increases upon photoisomerization. The ensuing photohardening of the polymeric network was corroborated using nanoindentation measurements. The bistability of the switch allowed us to lock-in and sustain multiple Tg values in the same polymeric material as a function of the hydrazone switch's Z/E isomer ratio, even at elevated temperatures. </p>