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Priimagi, Arri
Tampere University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Strategies to control humidity sensitivity of azobenzene isomerisation kinetics in polymer thin filmscitations
- 2022Multistage Reversible Tg Photomodulation and Hardening of Hydrazone-Containing Polymerscitations
- 2021Multistage Reversible Tg Photomodulation and Hardening of Hydrazone-Containing Polymerscitations
- 2020Fluorination of pyrene-based organic semiconductors enhances the performance of light emitting diodes and halide perovskite solar cellscitations
- 2020Fluorination of pyrene-based organic semiconductors enhances the performance of light emitting diodes and halide perovskite solar cellscitations
- 2019Low-dimensional formamidinium lead perovskite architectures via controllable solvent intercalationcitations
- 2019Eco-friendly and low-cost phenothiazine-based hole-transporting material for high performance perovskite solar cells
- 2018Programming Photoresponse in Liquid Crystal Polymer Actuators with Laser Projectorcitations
- 2018Thermal Isomerization of Hydroxyazobenzenes as a Platform for Vapor Sensingcitations
- 2017Self-Regulating Iris Based on Light-Actuated Liquid Crystal Elastomercitations
- 2017Crystallisation-enhanced bulk hole mobility in phenothiazine-based organic semiconductorscitations
- 2016Photoresponsive liquid-crystalline polymer films bilayered with an inverse opal structurecitations
- 2015From partial to complete optical erasure of azobenzene-polymer gratings effect of molecular weightcitations
- 2013Photoinduced surface patterning of azobenzene-containing supramolecular dendrons, dendrimers and dendronized polymerscitations
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article
Multistage Reversible Tg Photomodulation and Hardening of Hydrazone-Containing Polymers
Abstract
<p>The glass transition temperature (Tg) of a series of polyacrylate- and polymethacrylate-based polymers having bistable hydrazone photoswitches as pendants increases upon photoisomerization. The ensuing photohardening of the polymeric network was corroborated using nanoindentation measurements. The bistability of the switch allowed us to lock-in and sustain multiple Tg values in the same polymeric material as a function of the hydrazone switch's Z/E isomer ratio, even at elevated temperatures. </p>