| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Yang, Sihai
University of Manchester
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (32/32 displayed)
- 2024Electron Beam and Thermal Stabilities of MFM-300(M) Metal-Organic Frameworkscitations
- 2024Hierarchical porous metal-organic polyhedra for efficient oxidative cleavage of β-O-4 bonds in lignin model compound
- 2022Adsorption of sulphur dioxide in Cu(II)-carboxylate framework materials: the role of ligand functionalisation and open metal sites
- 2022Direct visualisation of supramolecular binding and separation of light hydrocarbons in MFM-300(In)
- 2022How reproducible are surface areas calculated from the BET equation?citations
- 2022How reproducible are surface areas calculated from the BET equation?citations
- 2022How Reproducible are Surface Areas Calculated from the BET Equation?citations
- 2022How Reproducible are Surface Areas Calculated from the BET Equation?citations
- 2021High Ammonia Adsorption in MFM-300 Materials:Dynamics and Charge Transfer in Host–Guest Bindingcitations
- 2021Catalytic decomposition of NO 2 over a copper-decorated metal–organic framework by non-thermal plasmacitations
- 2021High Ammonia Adsorption in MFM-300 Materialscitations
- 2021How Reproducible Are Surface Areas Calculated from the BET Equation?citations
- 2021Catalytic decomposition of NO2 over a copper-decorated metal–organic framework by non-thermal plasmacitations
- 2021Catalytic decomposition of NO2 over a copper-decorated metal–organic framework by non-thermal plasmacitations
- 2021Atomically-dispersed copper sites in a metal-organic framework for reduction of nitrogen dioxide
- 2021Simultaneous Neutron Powder Diffraction and Microwave Characterisation at Elevated Temperatures
- 2020Quantitative Electro-Reduction of CO2 to Liquid Fuel over Electro-Synthesized Metal-Organic Frameworkscitations
- 2020Quantitative Electro-Reduction of CO2 to Liquid Fuel over Electro-Synthesized Metal-Organic Frameworkscitations
- 2019Iodine adsorption in a redox-active metal-organic frameworkcitations
- 2019Iodine adsorption in a redox-active metal-organic framework:Electrical conductivity induced by host-guest charge-transfercitations
- 2018Ammonia Storage by Reversible Host-Guest Site Exchange in a Robust Metal-Organic Frameworkcitations
- 2018Ammonia Storage by Reversible Host-Guest Site Exchange in a Robust Metal-Organic Frameworkcitations
- 2018High Volumetric Hydrogen Adsorption in a Porous Anthracene-decorated Metal–Organic Frameworkcitations
- 2018High Volumetric Hydrogen Adsorption in a Porous Anthracene-decorated Metal–Organic Frameworkcitations
- 2018Enhancement of CO2 uptake and selectivity in a metal-organic framework by incorporation of thiophene functionalitycitations
- 2017Porous metal–organic polyhedral frameworks with optimal molecular dynamics and pore geometry for methane storagecitations
- 2017Stepwise Observation and Quantification and Mixed Matrix Membrane Separation of CO2 within a Hydroxy-Decorated Porous Hostcitations
- 2017Porous Metal–Organic Polyhedral Frameworks with Optimal Molecular Dynamics and Pore Geometry for Methane Storagecitations
- 2016Enhancement of CO2 Adsorption and Catalytic Properties by Fe-Doping of [Ga-2(OH)(2)(L)] (H4L = Biphenyl-3,3 ',5,5 '-tetracarboxylic Acid), MFM-300(Ga-2)citations
- 2014Inelastic neutron scattering study of binding of para-hydrogen in an ultra-microporous metal–organic frameworkcitations
- 2014A Novel Bismuth-Based Metal-Organic Framework for High Volumetric Methane and Carbon Dioxide Adsorptioncitations
- 2010Metal-Organic Polyhedral Frameworks: High H-2 Adsorption Capacities and Neutron Powder Diffraction Studies
Places of action
| Organizations | Location | People |
|---|
article
High Ammonia Adsorption in MFM-300 Materials
Abstract
Ammonia (NH3) is a promising energy resource owing to its high hydrogen density. However, its widespread application is restricted by the lack of efficient and corrosion-resistant storage materials. Here, we report high NH3 adsorption in a series of robust metal–organic framework (MOF) materials, MFM-300(M) (M = Fe, V, Cr, In). MFM-300(M) (M = Fe, VIII, Cr) show fully reversible capacity for >20 cycles, reaching capacities of 16.1, 15.6, and 14.0 mmol g–1, respectively, at 273 K and 1 bar. Under the same conditions, MFM-300(VIV) exhibits the highest uptake among this series of MOFs of 17.3 mmol g–1. In situ neutron powder diffraction, single-crystal X-ray diffraction, and electron paramagnetic resonance spectroscopy confirm that the redox-active V center enables host–guest charge transfer, with VIV being reduced to VIII and NH3 being oxidized to hydrazine (N2H4). A combination of in situ inelastic neutron scattering and DFT modeling has revealed the binding dynamics of adsorbed NH3 within these MOFs to afford a comprehensive insight into the application of MOF materials to the adsorption and conversion of NH3.