| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Boyer, Cyrille
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024Microphase Separation 3D Printing of Binary Inorganic Polymer Precursors to Prepare Nanostructured Carbon‐Ceramic Multimaterialscitations
- 2024Design and 3D Printing of Polyacrylonitrile‐Derived Nanostructured Carbon Architecturescitations
- 2023Microphase Separation 3D Printing of Binary Inorganic Polymer Precursors to Prepare Nanostructured Carbon‐Ceramic Multimaterialscitations
- 2023Exploiting NIR light mediated Surface-Initiated PhotoRAFT polymerization for orthogonal control polymer brushes and facile post-modification of complex architecture through opaque barrierscitations
- 2022Soft Liquid Metal Infused Conductive Spongescitations
- 2022P003 Synthetic antifungal peptide mimic kills <i>Candida albicans</i> by targeting protein glycosylation and synergistically prevents infection
- 2021Incorporation and antimicrobial activity of nisin Z within carrageenan/chitosan multilayerscitations
- 2018Discrete and Stereospecific Oligomers Prepared by Sequential and Alternating Single Unit Monomer Insertioncitations
- 2011High-order multiblock copolymers via iterative Cu(0)-mediated radical polymerizations (SET-LRP): Toward biological precisioncitations
- 2010Telechelic Diiodopoly(VDF-co-PMVE) Copolymers by Iodine Transfer Copolymerization of Vinylidene Fluoride (VDF) with Perfluoromethyl vinyl ether (PMVE)citations
- 2010Synthesis of hollow polymer nanocapsules exploiting gold nanoparticles as sacrificial templatescitations
- 2009Iodine Transfer Copolymerization of Vinylidene Fluoride and a-Trifluoromethacrylic Acid in Emulsion Process Without Any Surfactantscitations
- 2008Radical Terpolymerization of 1,1,2-Trifluoro-2-pentafluorosulfanylethylene and Pentafluorosulfanylethylene in the Presence of Vinylidene Fluoride and Hexafluoropropylene by Iodine Transfer Polymerizationcitations
- 2008Synthesis of triblock copolymers from glycolysed poly(ethylene terephthalate) by living radical polymerizationcitations
- 2007Synthesis and Characterisation of Organogels from ABA Triblock Copolymerscitations
- 2007Synthesis and Characterisation of Organogels from ABA Triblock Copolymerscitations
- 2006Kinetics of the iodine transfer polymerization of vinylidene fluoridecitations
- 2006Reverse Iodine Transfer Polymerization (RITP) of Methyl Methacrylatecitations
- 2006Poly(vinylidene fluoride)-b-poly(styrene) Block Copolymers by Iodine Transfer Polymerization (ITP): Synthesis, Characterization, and Kinetics of ITPcitations
- 2005Iodine Transfer Polymerization (ITP) of Vinylidene Fluoride (VDF). Influence of the Defect of VDF Chaining on the Control of ITPcitations
Places of action
| Organizations | Location | People |
|---|
article
High-order multiblock copolymers via iterative Cu(0)-mediated radical polymerizations (SET-LRP): Toward biological precision
Abstract
We report a new approach for the facile synthesis of high-order multiblock copolymers comprising very short blocks. The approach entails sequential addition of different monomers via an iterative single electron transfer - living radical polymerization technique, allowing nearly perfect control of the copolymer microstructure. It is possible to synthesize high-order multiblock copolymers with unprecedented control, i.e., A-B-C-D-E-etc., without any need for purification between iterative 24 h block formation steps. To illustrate this concept, we report the synthesis of model P(MA-b-MA...) homopolymer and P(MA-b-nBuA-b-EA-b-2EHA-b-EA-b-nBuA) copolymer in extremely high yield. Finally, the halide end-group can be modified via click chemistry , including thiol - bromide click chemistry, sodium methanethiosulfonate nucleophilic substitution, and atom transfer radical nitroxide coupling reaction, to yield functional, structurally complex macromolecules.