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Motta, Antonella |
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Graham, Darren M.
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article
Controlled synthesis of tuned bandgap nanodimensional alloys of PbS xSe1-x
Abstract
Truly alloyed PbS<sub>x</sub>Se<sub>1−x</sub> (x = 0−1) nanocrystals (∼5 nm in size) have been prepared, and their resulting optical properties are red-shifted systematically as the sulfur content of the materials increases. Their optical properties are discussed using a modified Vegard’s approach and the bowing parameter for these nanoalloys is reported for the first time. The alloyed structure of the nanocrystals is supported by the energy-filtered transmission electron microscope images of the samples, which show a homogeneous distribution of sulfur and selenium within the nanocrystals. X-ray photoelectron spectroscopy studies on ligand-exchanged nanocrystals confirmed the expected stoichiometry and various oxidized species.