| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Norrman, Kion
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (40/40 displayed)
- 2019Diluted Oxide Interfaces with Tunable Ground Statescitations
- 2018Oxygen Exchange and Transport in (La0.6Sr0.4)0.98FeO3-d – Ce0.9Gd0.1O1.95 Dual-Phase Compositescitations
- 2018High-temperature thermoelectric properties of Na- and W-Doped Ca3Co4O9 system citations
- 2018Oxygen Exchange and Transport in (La 0.6 Sr 0.4 ) 0.98 FeO 3-d – Ce 0.9 Gd 0.1 O 1.95 Dual-Phase Compositescitations
- 2017Mid-IR optical properties of silicon doped InPcitations
- 2017Dynamic and Impure Perovskite Structured Metal Oxide Surfacescitations
- 2016New Hypothesis for SOFC Ceramic Oxygen Electrode Mechanismscitations
- 2016In situ X-ray scattering of perovskite solar cell active layers roll-to-roll coated on flexible substratescitations
- 2016In situ X-ray scattering of perovskite solar cell active layers roll-to-roll coated on flexible substratescitations
- 2015Polarization Induced Changes in LSM Thin Film Electrode Composition Observed by In Operando Raman Spectroscopy and TOF-SIMS
- 2015Dynamic behavior of impurities and native components in model LSM microelectrodes on YSZcitations
- 2014TOF-SIMS characterization of impurity enrichment and redistribution in solid oxide electrolysis cells during operationcitations
- 2014TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devices – the ISOS-3 inter-laboratory collaborationcitations
- 2013Oxygen Electrode Kinetics and Surface Composition of Dense (La0.75Sr0.25)0.95MnO3 on YSZcitations
- 2013All polymer photovoltaics: From small inverted devices to large roll-to-roll coated and printed solar cellscitations
- 2013All polymer photovoltaics: From small inverted devices to large roll-to-roll coated and printed solar cellscitations
- 2013Oxygen Electrode Kinetics and Surface Composition of Dense (La 0.75 Sr 0.25 ) 0.95 MnO 3 on YSZcitations
- 2012TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devices - the ISOS-3 inter-laboratory collaborationcitations
- 2012TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devices - the ISOS-3 inter-laboratory collaborationcitations
- 2012Stability of Polymer Solar Cellscitations
- 2012Comprehensive Investigation of Silver Nanoparticle/Aluminum Electrodes for Copper Indium Sulfide/Polymer Hybrid Solar Cellscitations
- 2012TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devices–the ISOS-3 inter-laboratory collaborationcitations
- 2012Rapid flash annealing of thermally reactive copolymers in a roll-to-roll process for polymer solar cellscitations
- 2012TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devices – the ISOS-3 inter-laboratory collaborationcitations
- 2012TOF-SIMS investigation of degradation pathways occurring in a variety of organic photovoltaic devices – the ISOS-3 inter-laboratory collaborationcitations
- 2012Simultaneous multilayer formation of the polymer solar cell stack using roll-to-roll double slot-die coating from watercitations
- 2012Simultaneous multilayer formation of the polymer solar cell stack using roll-to-roll double slot-die coating from watercitations
- 2011Aqueous Processing of Low-Band-Gap Polymer Solar Cells Using Roll-to-Roll Methodscitations
- 2011Aqueous Processing of Low-Band-Gap Polymer Solar Cells Using Roll-to-Roll Methodscitations
- 2011Oxygen- and water-induced degradation of an inverted polymer solar cell: the barrier effectcitations
- 2011Water and oxygen induced degradation of small molecule organic solar cellscitations
- 2010Using Light-Induced Thermocleavage in a Roll-to-Roll Process for Polymer Solar Cellscitations
- 2010Degradation Patterns in Water and Oxygen of an Inverted Polymer Solar Cellcitations
- 2010Degradation Patterns in Water and Oxygen of an Inverted Polymer Solar Cellcitations
- 2010Stability and Degradation of Polymer Solar cells
- 2009Water-Induced Degradation of Polymer Solar Cells Studied by (H2O)-O-18 Labelingcitations
- 2008Effects of trace elements at the Ni/ScYSZ interface in a model solid oxide fuel cell anodecitations
- 2007Analysis of the failure mechanism for a stable organic photovoltaic during 10 000 h of testingcitations
- 2006Lifetimes of organic photovoltaics: Design and synthesis of single oligomer molecules in order to study chemical degradation mechanismscitations
- 2006Oxygen release and exchange in niobium oxide MEHPPV hybrid solar cellscitations
Places of action
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article
Degradation Patterns in Water and Oxygen of an Inverted Polymer Solar Cell
Abstract
The spatial distribution of reaction products in multilayer polymer solar cells induced by water and oxygen atmospheres was mapped and used to elucidate the degradation patterns and failure mechanisms in an inverted polymer solar cell. The active material comprised a bulk heterojunction formed by poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) sandwiched between a layer of zinc oxide and a layer of poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS) that acted as, respectively, electron and hole transporting layers between the active material and the two electrodes indium−tin−oxide (ITO) and printed silver. X-ray photoelectron spectroscopy (XPS) and time-of-flight secondary ion mass spectrometry (TOF-SIMS) in conjunction with isotopic labeling using H218O and 18O2 enabled detailed information on where and to what extent uptake took place. A comparison was made between the use of a humid (oxygen-free) atmosphere and a dry oxygen atmosphere during testing of devices that were kept in the dark and devices that were subjected to illumination under simulated sunlight. It was found that the reactions taking place at the interface between the active layer and the PEDOT:PSS were the major cause of device failure in the case of these inverted devices, which are compatible with full roll-to-roll (R2R) coating and industrial manufacture. The PEDOT:PSS was found to phase separate, with the PEDOT-rich phase being responsible for most of the interface degradation in oxygen atmospheres. In water atmospheres, little chemically induced degradation was observed, whereas a large partially reversible dependence of the open circuit voltage on the relative humidity was observed. In addition, temporal aspects are discussed in regard to degradation mechanisms. Finally, analytical aspects in regard to storing devices are discussed.