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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bunk, Oliver
Humboldt-Universität zu Berlin
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2020 Between V2 and V3: Processing non-canonical sentence structures in L2 German
- 2018Small-angle X-ray scattering tensor tomography : Model of the three-dimensional reciprocal-space map, reconstruction algorithm and angular sampling requirementscitations
- 2016Ultrastructure Organization of Human Trabeculae Assessed by 3D sSAXS and Relation to Bone Microarchitecturecitations
- 20153D scanning SAXS: A novel method for the assessment of bone ultrastructure orientationcitations
- 2015Nanostructure surveys of macroscopic specimens by small-angle scattering tensor tomographycitations
- 2013Density mapping of hardened cement paste using ptychographic X-ray computed tomographycitations
- 2010Comparison of quasistatic to impact mechanical properties of multiwall carbon nanotube/polycarbonate compositescitations
- 2005Structure of zone-cast HBC-C 1 2 H 2 5 filmscitations
- 2005Structure of zone-cast HBC-C12H25 filmscitations
- 2003Induced alignment of a solution-cast discotic hexabenzocoronene derivative for electronic devices investigated by surface X-ray diffractioncitations
Places of action
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article
Induced alignment of a solution-cast discotic hexabenzocoronene derivative for electronic devices investigated by surface X-ray diffraction
Abstract
A surface X-ray diffraction study is presented showing that highly ordered and uniaxially aligned hexa(3,7-dimethyl-octanyl)hexa-peri-hexabenzocoronene (HBC-C8,2) films can be fabricated by crystallization from solution onto friction-transferred poly(tetrafluoroethylene) (PTFE) layers. Three crystalline HBC-C8,2 majority phases result. In all three phases, the HBC-C8,2 molecules self-organize into columns which are uniaxially aligned along the direction defined by the PTFE macromolecules of the substrate. The three phases are quite similar, the major difference being their orientation with respect to the substrate. A quasi-2D epitaxial growth mechanism with a grapho-epitaxial component for one of the three phases explains the formation of the three rotational HBC-C8,2 variants. A method to obtain a thin film with only one phase is proposed. The results show that standard Theta-2Theta X-ray diffraction and transmission electron diffraction can be very misleading tools to estimate the crystalline quality in a thin film of complex structure.