Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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Materials Map under construction

The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (2/2 displayed)

  • 2001CN radical hydrogenation from solid H 2 reactions, an alternative way of HCN formation in the interstellar medium35citations
  • 2001Experimental and quantum study of adsorption of ozone (O-3) on amorphous water ice film40citations

Places of action

Chart of shared publication
Borget, Fabien
2 / 2 shared
Sander, Wolfram
1 / 4 shared
Vinogradoff, Vassilissa
1 / 2 shared
Theulé, Patrice
1 / 1 shared
Grote, Dirk
1 / 2 shared
Müller, Sandra
1 / 1 shared
Aycard, Jean-Pierre
1 / 1 shared
Allouche, Alain
1 / 1 shared
Chart of publication period
2001

Co-Authors (by relevance)

  • Borget, Fabien
  • Sander, Wolfram
  • Vinogradoff, Vassilissa
  • Theulé, Patrice
  • Grote, Dirk
  • Müller, Sandra
  • Aycard, Jean-Pierre
  • Allouche, Alain
OrganizationsLocationPeople

article

CN radical hydrogenation from solid H 2 reactions, an alternative way of HCN formation in the interstellar medium

  • Borget, Fabien
  • Sander, Wolfram
  • Chiavassa, Thierry
  • Vinogradoff, Vassilissa
  • Theulé, Patrice
  • Grote, Dirk
  • Müller, Sandra
Abstract

Context. Molecular hydrogen (H 2) is the most abundant molecule of the interstellar medium (ISM) in gas phase and it has been assumed to exist in solid state or as coating on grains. Aims. Our goal is to show that solid H 2 can act as a hydrogenation agent, reacting with CN radicals to form HCN. Methods. In a H 2 matrix, we studied the hydrogenation of the CN radical generated from the vacuum ultraviolet photolysis (VUV-photolysis) of C 2 N 2 at 3.8 K. We modified the wavelengths and the host gas in order to be sure that CN radicals can abstract H from H 2 molecules. Results. HCN monomers, dimers, and oligomers have been characterised by Fourier transform infrared spectroscopy (FTIR). H 2 CN as well as CN radicals have also been clearly observed during the photolysis performed at 3.8 K. Conclusions. H 2 is a hydrogenation reagent towards CN radicals producing HCN. This type of reaction should be taken into account for the reactivity at low temperature in contaminated H 2 ice macro-particles (CHIMPs), H 2 flakes or in the first sublayers of grains where solid H 2 has accumulated.

Topics
  • impedance spectroscopy
  • grain
  • Hydrogen
  • gas phase
  • Fourier transform infrared spectroscopy