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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Goderis, B.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2017Effect of the GO reduction method on the dielectric properties, electrical conductivity and crystalline behavior of PEO/rGO nanocompositescitations
- 2016Effect of compression on the molecular arrangement of Itraconazole−Soluplus solid dispersions : induction of liquid crystals or exacerbation of phase separation?citations
- 2015Linking the morphology of a high hard segment content polyurethane to its thermal behaviour and mechanical propertiescitations
- 2015Curing kinetics and morphology of a nanovesicular epoxy/stearyl-block-poly(ethylene oxide) surfactant systemcitations
- 2010Symmetry and electronic states of Mn<sup>2+</sup> in ZnS nanowires with mixed hexagonal and cubic stackingcitations
- 2009Thermotropic Ruthenium(II)-Containing Metallomesogens Based on Substituted 1,10-Phenanthroline Ligandscitations
- 2008Liquid-crystalline ternary rare-earth complexescitations
- 2008Imidazolium ionic liquid crystals with pendant mesogenic groupscitations
- 2007Magnetic alignment study of rare-earth-containing liquid crystalscitations
- 2003Influence of the chain length on the thermal behavior of lanthanide(III) 4-alkoxybenzoatescitations
- 2003Adducts of Schiff bases with tris(β-diketonato)lanthanide(III) complexes: Structure and liquid-crystalline behaviour
Places of action
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article
Thermotropic Ruthenium(II)-Containing Metallomesogens Based on Substituted 1,10-Phenanthroline Ligands
Abstract
Imidazo[4,5-f]-1,10-phenanthroline and pyrazino[2,3-f]-1,10-phenanthroline substituted with long alkyl chains are versatile ligands for the design of metallomesogens because of the ease of ligand substitution. Whereas the ligands and the corresponding rhenium(I) complexes were not liquid-crystalline, mesomorphism was observed for the corresponding ionic ruthenium(II) complexes with chloride, hexafluorophosphate, and bistriflimide counterions. The mesophases were identified as smectic A phases by high-temperature small-angle X-ray scattering (SAXS) using synchrotron radiation. The transition temperatures depend on the anion, the highest temperatures being observed for the chloride salts and the lowest for the bistriflimide salts. The ruthenium(II) complexes are examples of luminescent ionic liquid crystals.