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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Volkmer, Dirk
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2022Viscoelasticity and energy dissipation as indicators of flexural fatigue behavior in a ductile carbon fiber-reinforced cementitious compositecitations
- 20213D printing as an automated manufacturing method for a carbon fiber-reinforced cementitious composite with outstanding flexural strength (105 N/mm2)citations
- 2021Influence of fiber alignment on pseudoductility and microcracking in a cementitious carbon fiber composite materialcitations
- 2020CFA-18 : a homochiral metal-organic framework (MOF) constructed from rigid enantiopure bistriazolate linker moleculescitations
- 2017Magnetodielectric coupling in a non-perovskite metal-organic frameworkcitations
- 2015Selective growth of MFU-4l single crystals on microstructured plasma polymer coatingscitations
- 2014Dielectric Relaxation Processes, Electronic Structure and Band Gap Engineering of MFU-4-type Metal-Organic Frameworks: Towards a Rational Design of Semiconducting Microporous Materialscitations
- 2013CFA-2 and CFA-3 (Coordination Framework Augsburg University-2 and -3) novel MOFs assembled from trinuclear Cu(I)/Ag(I) secondary building units and 3,3',5,5'-tetraphenyl-bipyrazolate ligandscitations
- 2013Microdomain transformations in mosaic mesocrystal thin filmscitations
- 2013A metallosupramolecular octahedron assembled from twelve copper(I) metal ions and six 4,4' -(1,2-phenylene)bis(3,5-dimethylpyrazol-1-ide) ligandscitations
- 2013New VIV-based metal-organic framework having framework flexibility and high CO2 adsorption capacitycitations
- 2012The existence region and composition of a polymer-induced liquid precursor phase for DL-glutamic acid crystalscitations
- 2011Hierarchical DL-Glutamic acid microspheres from polymer-induced liquid precursorscitations
- 20113D characterization of microstructured poly(methacrylic acid) thin films via Mach–Zehnder interference microscopycitations
- 2006Polymer brushes as ionotropic matrices for the directed fabrication of microstructured calcite thin filmscitations
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article
New VIV-based metal-organic framework having framework flexibility and high CO2 adsorption capacity
Abstract
<p>A vanadium based metal-organic framework (MOF), VO(BPDC) (BPDC<sup>2-</sup> = biphenyl-4,4′-dicarboxylate), adopting an expanded MIL-47 structure type, has been synthesized via solvothermal and microwave methods. Its structural and gas/vapor sorption properties have been studied. This compound displays a distinct breathing effect toward certain adsorptives at workable temperatures. The sorption isotherms of CO<sub>2</sub> and CH<sub>4</sub> indicate a different sorption behavior at specific temperatures. In situ synchrotron X-ray powder diffraction measurements and molecular simulations have been utilized to characterize the structural transition. The experimental measurements clearly suggest the existence of both narrow pore and large pore forms. A free energy profile along the pore angle was computationally determined for the empty host framework. Apart from a regular large pore and a regular narrow pore form, an overstretched narrow pore form has also been found. Additionally, a variety of spectroscopic techniques combined with N<sub>2</sub> adsorption/desorption isotherms measured at 77 K demonstrate that the existence of the mixed oxidation states V<sup>III</sup>/V<sup>IV</sup> in the titled MOF structure compared to pure V<sup>IV</sup> increases the difficulty in triggering the flexibility of the framework.</p>