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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Vaughan, Gavin
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2023Denser glasses relax faster: Enhanced atomic mobility and anomalous particle displacement under in-situ high pressure compression of metallic glassescitations
- 2023Mapping the structural trends in zinc aluminosilicate glassescitations
- 20225D total scattering computed tomography reveals the full reaction mechanism of a bismuth vanadate lithium ion battery anodecitations
- 2021Hydrogen Sorption Properties of a Novel Refractory Ti-V-Zr-Nb-Mo High Entropy Alloycitations
- 2015Structural evolution in Ti-Cu-Ni metallic glasses during heating
- 2015In situ monitoring of phase transformation microstructures at Earth's mantle pressure and temperature using multi-grain XRDcitations
- 2015In situ monitoring of phase transformation microstructures at Earth's mantle pressure and temperature using multi-grain XRDcitations
- 2014Evolution of atomic structure during nanoparticle formationcitations
- 2012Structural Modulation and Phase Transitions in La2CoO4.14 Investigated by Synchrotron X-ray and Neutron Single-Crystal Diffractioncitations
- 2012Structural Modulation and Phase Transitions in La2CoO4.14 Investigated by Synchrotron X-ray and Neutron Single-Crystal Diffractioncitations
- 2011Structural and mechanical characterization of Zr58.5Ti8.2Cu14.2Ni11.4Al7.7 bulk metallic glass
- 2004Self propagating high temperature synthesis of magnesium zinc ferrites (MgxZn1-xFe2O3): Thermal imaging and time resolved X-ray diffraction experimentscitations
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article
Structural Modulation and Phase Transitions in La2CoO4.14 Investigated by Synchrotron X-ray and Neutron Single-Crystal Diffraction
Abstract
We report a combined synchrotron X-ray and neutron diffraction study on as-grown La2CoO4.14 single-crystal from 10 to 470 K. Unprecedented structural features in terms of a (3 + 2)D incommensurate modulation have been detected and characterized in the Low Temperature Orthorhombic (LTO) phase already at room temperature despite the complex twinning that was unravelled. A new intermediate phase between the LTO and High Temperature Tetragonal (HTT) phases has been observed for the first time (in the range of 413?433 K). The transformation from LTO to this so-called HTLO (High Temperature Less Orthorhombic) phase is associated to a lowering of orthorhombicity and a loss of one modulation vector, yielding a (3 + 1)D incommensurate modulation. Conversely, above 433 K the HTT phase appears as nonmodulated but exhibits a strong dynamic disorder of CoO6 octahedra, which has been characterized in detail by reconstruction of nuclear densities via the Maximum Entropy Method (MEM).