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Bendix, Jesper
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Publications (5/5 displayed)
- 2024An approach for patterned molecular adsorption on ferromagnets, achieved via Moiré superstructures
- 2022Photophysical Integrity of the Iron(III) Scorpionate Framework in Iron(III)-NHC Complexes with Long-Lived 2LMCT Excited Statescitations
- 2021Island formation of Er(trensal) single-ion magnets on graphene observed on the micrometer scalecitations
- 2018Rational self-assembly of tricobalt extended metal atom chains and [MF6]2– building blocks into one-dimensional coordination polymerscitations
- 2011Metallocorrole Dendrimerscitations
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article
Metallocorrole Dendrimers
Abstract
The corrole–chromium(V)–nitrido moiety is introduced as a uniquely sensitive EPR spin probe. We describe a series of corrole-centered poly(amidoamine) (PAMAM) dendrimers and the selective incorporation of the chromium(V)–nitrido moiety. The chromium–corrole cores are reactive toward both neutral and charged reagents, and the accessibility of the dendrimer cores enables easy manipulation of the spin probe. The spin probe reveals a pronounced solvent dependence of the solution-phase structure of the dendrimers.