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Christensen, Jørn Bolstad
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Publications (7/7 displayed)
- 2024Macromolecular Pairing On Nanoparticle Surface Modulates Immune Response
- 2023Empowering Antibiotics In The Amr Landscape: Insights From Dendrimer Conjugation In Ali Systems
- 2012Dendrimers, dendrons and dendritic polymers
- 2011Metallocorrole Dendrimerscitations
- 2009Microwave-assisted McMurry polymerization utilizing low-valent titanium for the synthesis of poly 2,6-[1,5-bis(dodecyloxy)naphthylene vinylene] (PNV)citations
- 2009Dendrimers, dendrons, and dendritic polymerscitations
- 2004Guest-host chemistry with dendrimers: Stable polymer assemblies by rational design
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article
Metallocorrole Dendrimers
Abstract
The corrole–chromium(V)–nitrido moiety is introduced as a uniquely sensitive EPR spin probe. We describe a series of corrole-centered poly(amidoamine) (PAMAM) dendrimers and the selective incorporation of the chromium(V)–nitrido moiety. The chromium–corrole cores are reactive toward both neutral and charged reagents, and the accessibility of the dendrimer cores enables easy manipulation of the spin probe. The spin probe reveals a pronounced solvent dependence of the solution-phase structure of the dendrimers.