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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lodeiro, Carlos
Universidade Nova de Lisboa
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (25/25 displayed)
- 2023Diphenyl ditelluride assisted synthesis of noble metal-based silver-telluride 2D organometallic nanofibers with enhanced aggregation-induced emission (AIE) after oleylamine treatment
- 2020Thermochromic and acidochromic properties of polymer films doped with pyridyl-β-diketonate boron(III) complexescitations
- 2020Aggregation-induced emission enhancement (AIEE)-active Pt(II) metallomesogens as dyes sensitive to Hg2+ and dopant agents to develop stimuli-responsive luminescent polymer materialscitations
- 2019Highly accessible aqueous synthesis of well-dispersed dendrimer type platinum nanoparticles and their catalytic applicationscitations
- 2019Exploring the control in antibacterial activity of silver triangular nanoplates by surface coating modulationcitations
- 2017Synthesis and Characterization of PtTe2 Multi-Crystallite Nanoparticles using Organotellurium Nanocompositescitations
- 2017Supercritical CO2-assisted spray drying of strawberry-like gold-coated magnetite nanocomposites in chitosan powders for inhalationcitations
- 2017Synthesis and characterization of PtTeâ‚‚ multi-crystallite nanoparticles using organotellurium nanocomposites
- 2017A seleno-pyrene selective probe for Hg2+ detection in either aqueous or aprotic systemscitations
- 2016The interaction of Hg2+ and trivalent ions with two new fluorescein bio-inspired dual colorimetric/fluorimetric probescitations
- 2016Study of multiporphyrin compounds as colorimetric sitting-atop metal complexescitations
- 2016Novel trans-disubstituted hexaaza-macrocyclic ligands containing pyridine head units: Synthesis, disubstitution and colorimetric propertiescitations
- 2015Novel nanocomposites based on a strawberry-like gold- coated magnetite (Fe@Au) for protein separation in multiple myeloma serum samplescitations
- 2014Columnar discotic Pt(II) metallomesogens as luminescence multifunctional materials with chemo and thermosensor abilitiescitations
- 2014A new 3,5-bisporphyrinylpyridine derivative as a fluorescent ratiometric probe for zinc ionscitations
- 2014Bioinspired Functionalized Nanoparticles as Tools for Detection, Quantification and Targeting of Biomolecules
- 2013Zn 2+ /Cd 2+ optical discrimination by fluorescent chemosensors based on 8-hydroxyquinoline derivatives and sulfur-containing macrocyclic unitscitations
- 2013Zn2+/Cd2+ optical discrimination by fluorescent chemosensors based on 8-hydroxyquinoline derivatives and sulfur-containing macrocyclic unitscitations
- 2012New quinoline α-diimine ligands as fluorescent probes for metal ions: Ultrasound-assisted and conventional synthetic methodscitations
- 2012Novel emissive phenylurea-based macrocyclic chemosensor: Synthesis, fluorescent and complexation studiescitations
- 2012Novel emissive podands based on 8-OH-quinoline: Synthesis, fluorescence materials, DFT and complexation studiescitations
- 2011Novel small stable gold nanoparticles bearing fluorescent cysteine-coumarin probes as new metal-modulated chemosensorscitations
- 2011Bio-inspired systems for metal ion sensing : new emissive peptide probes based on benzo[d]oxazole derivatives and their gold and silica nanoparticlescitations
- 2010Hg2+ detection by new anthracene pendant-arm derivatives of mixed N/S- and N/S/O-donor macrocycles: Fluorescence, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and density functional theory studiescitations
- 2003Complexation of aluminum(III) by anthocyanins and synthetic flavylium salts: a source for blue and purple colorcitations
Places of action
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article
Hg2+ detection by new anthracene pendant-arm derivatives of mixed N/S- and N/S/O-donor macrocycles: Fluorescence, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and density functional theory studies
Abstract
<p>The optical response of four new anthracenylmethyl pendant-arm derivatives (L1-L4) of the macrocyclic ligands [12]aneNS<sub>3</sub>, [12]aneNS <sub>2</sub>O, [15]aneNS<sub>2</sub>O<sub>2</sub>, and [12]aneN<sub>2</sub>SO toward the metal ions Zn<sup>2+</sup>, Cd<sup>2+</sup>, Pb<sup>2+</sup>, Cu <sup>2+</sup>, Hg<sup>2+</sup>, Ag<sup>+</sup>, Fe<sup>2+</sup>, Co <sup>2+</sup>, Ni<sup>2+</sup>, Mn<sup>2+</sup>, Ca<sup>2+</sup>, Na <sup>+</sup>, Mg<sup>2+</sup>, and K<sup>+</sup> was investigated in 1:1 (v/v) MeCN/H<sub>2</sub>O solutions. A strong chelation enhancement of quenching effect was observed on the fluorescent emission intensity of L2 as a consequence of the host-guest interaction with Hg<sup>2+</sup> and the formation of a 1:2 metal-to-ligand complex. Density functional theory calculations confirmed the formation of a sandwich-type complex between L2 and Hg<sup>2+</sup> as a favorable process. A matrix-assisted laser desorption/ionization (MALDI) time-of-flight mass spectrometry study using the four ligands as active MALDI probes was also performed. L1-L4 have also been explored as fluorescence chemosensors in microsamples using NANODROP technology.</p>