| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Fletcher, Ashleigh
University of Strathclyde
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2021Advancing computational analysis of porous materials – modelling three-dimensional gas adsorption in organic gelscitations
- 2021Multi-stimulus linear negative expansion of a breathing M(O2CR)4-node MOFcitations
- 2020Adsorption of Pb(II) ions from contaminated water by 1, 2, 3, 4-butanetetracarboxylic acid-modified microcrystalline cellulosecitations
- 2018Fiber-reinforced organic polymer aerogel
- 2016Scalable continuous solvothermal synthesis of metal organic framework (MOF-5) crystalscitations
- 2015Coordination polymer flexibility leads to polymorphism and enables a crystalline solid-vapour reactioncitations
- 2013Chemical transformations of a crystalline coordination polymercitations
- 2013Effect of synthesis conditions on formation pathways of metal organic framework (MOF-5) Crystalscitations
- 2006Assembly of heterometallic clusters and coordination polymers by combining Mo-S-based clusters with Mn2+citations
- 2004Adsorption of gases and vapors on nanoporous Ni-2(4,4 '-bipyridine)(3)(NO3)(4) metal-organic framework materials templated with methanol and ethanol: Structural effects in adsorption kineticscitations
- 2001Adsorption dynamics of gases and vapors on the nanoporous metal organic framework material Ni-2(4,4 '-bipyridine)(3)(NO3)(4): guest modification of host sorption behaviorcitations
Places of action
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article
Assembly of heterometallic clusters and coordination polymers by combining Mo-S-based clusters with Mn2+
Abstract
Addition of [(Mo2O2S2)-O-V(edt)(2)](2-) (edt) 1,2-ethanedithiolate) to acetonitrile and/ or methanol solutions of Mn-II containingbipyridines [4,4'-trimethylenedipyridine (TDP), 4,4'-bipyridine(4,4'-bpy), 2,2'-bipyridine (2,2'-bpy)] or 15-crown-5 produces threenew heterometallic cluster coordination polymers,[Mn-2{Mo2O2S2(edt)(2)}(2)( TDP)(3)(CH3OH)(2)( NCMe)(2)], 3CH3OHcenter dot 0.25MeCN (1),[Mn(TDP)(2)(H2O)(2)](2+)[Mn{Mo2O2S2(edt)(2))(2)(TDP)(2)}](2-),6CH(3)OH (2), [Mn{Mo2O2S2(edt)(2)}(TDP)(2)( CH3OH)(H2O)]center dotCH3OH (3), and three new multinuclear clusters,[Mn{Mo2O2S2(edt)(2)}(4,4'-bpy)(CH3OH)(4)]center dot 0.5(4,4'-bpy)(4), [Mn{Mo2O2S2(edt)(2)}(2,2'-bpy)(2)]center dot 2CH(3)OH ( 5),and (NEt4)(2)[Mn(15-crown-5) {Mo2O2S2(edt)(2)}(2)] ( 6). Allcompounds were characterized by X-ray crystallography. The coordinationmode of Mn in these compounds depends on the ligands and thecrystallization conditions. Compound 2 readily converts to 1 or 3depending on the reaction and solvent conditions. Compounds 1 and 2were analyzed using thermogravimetric analysis combined with massspectroscopy (TG-MS) in the temperature range 25-500 degrees C. Theroom-temperature magnetic moments for compounds 1-6 were determined.