• Ipser, Herbert
• Schmetterer, Clemens
• Ganesan, Rajesh
• Richter, Klaus W.
• Effenberger, Herta Silvia

Abstract

The isopiestic technique was employed to to provide optimum conditions for the formation of a binary or ternary target compound in which one of the components is volatile, that could even be employed for bulk synthesis or commercial production of metal phosphides. The crystal structure itself was determined by single-crystal X-ray diffraction where the cell metrics and intensity distribution was obtained from a powder pattern. The individual samples are weighted number of times and their compositions are derived from the mass difference which is attributed to the uptake of phosphorus. The experiment also revealed that white phosphorus condenses in the reservoir at the lowest temperature as the vapor pressure of white phosphorus is dominant over that of the red modification, the phosphorus vapor pressure in the apparatus is clearly defined by the temperature of the reservoir of white phosphorus, in semiconducting electronics, as anode materials.

Topics

• impedance spectroscopy
• compound
• phase
• x-ray diffraction
• experiment
• Phosphorus