| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Kamperman, Marleen
University of Groningen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (26/26 displayed)
- 2024Structure-Property Relationships of Granular Hybrid Hydrogels Formed through Polyelectrolyte Complexationcitations
- 2024Structure–Property Relationships of Granular Hybrid Hydrogels Formed through Polyelectrolyte Complexationcitations
- 2023Electrically Conductive and Highly Stretchable Piezoresistive Polymer Nanocomposites via Oxidative Chemical Vapor Depositioncitations
- 2023Electrically Conductive and Highly Stretchable Piezoresistive Polymer Nanocomposites via Oxidative Chemical Vapor Depositioncitations
- 2023Melt electrowritten scaffolds containing fluorescent nanodiamonds for improved mechanical properties and degradation monitoringcitations
- 2023Effect of Dynamically Arrested Domains on the Phase Behavior, Linear Viscoelasticity and Microstructure of Hyaluronic Acid - Chitosan Complex Coacervatescitations
- 2023Effect of Dynamically Arrested Domains on the Phase Behavior, Linear Viscoelasticity and Microstructure of Hyaluronic Acid - Chitosan Complex Coacervatescitations
- 2023Hydrophobically modified complex coacervates for designing aqueous pressure-sensitive adhesivescitations
- 2023Hydrophobically modified complex coacervates for designing aqueous pressure-sensitive adhesivescitations
- 2018Microphase segregation of diblock copolymers studied by the self-consistent field theory of Scheutjens and Fleercitations
- 2017Statistical Paradigm for Organic Optoelectronic Devices : Normal Force Testing for Adhesion of Organic Photovoltaics and Organic Light-Emitting Diodescitations
- 2017Statistical Paradigm for Organic Optoelectronic Devicescitations
- 2015The effect of molecular composition and crosslinking on adhesion of a bio-inspired adhesivecitations
- 2013Towards mesoporous Keggin-type polyoxometalates-systematic study on organic template removalcitations
- 2012A silica sol-gel design strategy for nanostructured metallic materialscitations
- 2012Direct synthesis of inverse hexagonally ordered diblock copolymer/polyoxometalate nanocomposite filmscitations
- 2011Nanocomposite characterization on multiple length scales using μSAXScitations
- 2010Nanomanufacturing of continuous composite nanofibers with confinement-induced morphologiescitations
- 2010Block copolymer directed nanoporous metal thin filmscitations
- 2009Metal nanoparticle - block copolymer composite assembly and disassemblycitations
- 2009Morphology diagram of a diblock copolymer - aluminosilicate nanoparticle systemcitations
- 2008Ordered mesoporous materials from metal nanoparticle-block copolymer self-assemblycitations
- 2008Morphology control in block copolymer/polymer derived ceramic precursor nanocompositescitations
- 2008Direct access to thermally stable and highly crystalline mesoporous transition-metal oxides with uniform porescitations
- 2006Self-assembled structures in electrospun poly(styrene-block-isoprene) fiberscitations
- 2004Ordered mesoporous ceramics stable up to 1500 °C from diblock copolymer mesophasescitations
Places of action
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article
Morphology diagram of a diblock copolymer - aluminosilicate nanoparticle system
Abstract
We explore the morphology space of nanocomposites prepared from poly(isoprene-block-ethylene oxide) (PI-b-PEO) diblock copolymers as structure directing agents for aluminosilicate nanoparticles prepared from (3-glycidyloxypropyl)trimethoxysilane (GLYMO) and aluminum(III) sec-butoxide. The results of structural investigations of over 60 polymer-inorganic nanocomposites are reported. They are obtained from 12 different block copolymers of varying molecular weight (10-100 kg/mol) and PEO weight fraction (fw 0.1-0.8) through addition of different amounts of inorganic components. Eight different morphologies as well as composites with biphasic character are observed. Individual block copolymers show up to five different well-defined morphologies upon addition of the inorganic sols. Differential scanning calorimetry (DSC) studies on the composites show that the addition of the inorganic components suppresses PEO crystallization when the inorganic to PEO weight fraction ratio of the composites is greater than 1.3-1.5. The eight phases are mapped out using two- and three-component morphology diagrams.