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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Khimyak, Yaroslav Z.
University of East Anglia
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Surface modification of cellulose nanomaterials with amine functionalized fluorinated ionic liquids for hydrophobicity and high thermal stabilitycitations
- 2024Self-healing composite coating fabricated with a cystamine crosslinked cellulose nanocrystal stabilized Pickering emulsioncitations
- 2022Amphiphilic Cellulose Nanocrystals for Aqueous Processing of Thermoplastics:ACS Applied Polymer Materialscitations
- 2022Amphiphilic cellulose nanocrystals for aqueous processing of thermoplasticscitations
- 2019Thermosensitive supramolecular and colloidal hydrogels via self-assembly modulated by hydrophobized cellulose nanocrystalscitations
- 2018Nanocrystallization of rare tolbutamide form V in mesoporous MCM-41 silicacitations
- 201619F NMR spectroscopy as a highly sensitive method for the direct monitoring of confined crystallization within nanoporous materialscitations
- 2016Structure and mobility of lactose in lactose/sodium montmorillonite nanocompositescitations
- 2016Structural properties, order-disorder phenomena and phase stability of orotic acid crystal formscitations
- 2010Chemical bonding assembly of multifunctional oxide nanocompositescitations
- 2009Reversible methane storage in a polymer-supported semi-clathrate hydrate at ambient temperature and pressurecitations
- 2008Bulk superconductivity at 38 K in a molecular systemcitations
- 2006Methylaminated potassium fulleride, (CH3NH2)K 3C60: Towards hyperexpanded fulleride latticescitations
Places of action
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article
Reversible methane storage in a polymer-supported semi-clathrate hydrate at ambient temperature and pressure
Abstract
A key issue regarding the use of clathrates and semi-clathrate hydrates for practical gas storage is the pressure-temperature stability of the material. For many practical applications, the avoidance of cooling, gas overpressure, and mechanical mixing would be very desirable. Here, we show that porous emulsion-templated polymer supports greatly enhance methane uptake kinetics in tetra-iso-amylammonium bromide semi-clathrate hydrates without introducing complex mixing technologies. These systems show unprecedented thermal stability and can be decomposed upon demand to release the gas. Single crystal X-ray structure analysis of the semi-clathrates loaded with methane or krypton were obtained, confirming that the gases are stored in the dodecahedral A' and A'' cages.