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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Dujardin, Christophe
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024Energy deposition in liquid scintillators composed of CsPbBr3 colloidal nanocrystals dispersionscitations
- 2024Catalytic abatement of NO and N2O from nitric acid plants: A novel approach using noble metal-modified perovskitescitations
- 2024Real-time detection and discrimination of radioactive gas mixtures using nanoporous inorganic scintillatorscitations
- 2024Nanoparticle-based scintillating aerogels for real-time radioactive gas detection
- 2022Highly luminescent scintillating hetero-ligand MOF nanocrystals with engineered Stokes shift for photonic applicationscitations
- 2022(Pb,Sr)TiO3 Films on SrTiO3 (100) Substrates Grown by Liquid Phase Epitaxy
- 2022Porous composites based on scintillating metal-organic frameworks nanocrystals for radioactive gas detection.
- 2022Doping MAPbBr 3 hybrid perovskites with CdSe/CdZnS quantum dots: from emissive thin films to hybrid single-photon sourcescitations
- 2021Trapping Mechanisms and Delayed Recombination Processes in Scintillating Ce-Doped Sol–Gel Silica Fiberscitations
- 2020Quest to enhance up-conversion efficiency: a comparison of anhydrous vs. hydrous synthesis of NaGdF4: Yb3+ and Tm3+ nanoparticlescitations
- 2019On the use of CdSe scintillating nanoplatelets as time taggers for high-energy gamma detectioncitations
- 2019Precursor-directed synthesis of upconverting LiYF4:Yb3+, Tm3+ nanoparticles and their composites designed for near infra-red driven photocatalysis
- 2019Optimization of the composition of perovskite type materials for further elaboration of four-way catalysts for gasoline enginecitations
- 2018Needs, Trends, and Advances in Inorganic Scintillatorscitations
- 2018Design and Application of High Optical Quality YAG:Ce Nanocrystal-Loaded Silica Aerogelscitations
- 2018Radio-luminescence spectral features and fast emission in hafnium dioxide nanocrystalscitations
- 2016Enhanced Transparency through Second Phase Crystallization in BaAl4O7 Scintillating Ceramicscitations
- 2016Epitaxial growth of gadolinium and lutetium-based aluminum perovskite thin films for X-ray micro-imaging applicationscitations
- 2015Rational preparation of Ag and Au bimetallic catalysts for the hydrocarbon-SCR of NOx: Sequential deposition vs. coprecipitation methodcitations
- 2015Catalytic abatement of NO and N2O from nitric acid plants: A novel approach using noble metal-modified perovskitescitations
- 2013Perfectly Transparent Sr3Al2O6 Polycrystalline Ceramic Elaborated from Glass Crystallizationcitations
- 2013Perfectly Transparent Sr3Al2O6 Polycrystalline Ceramic Elaborated from Glass Crystallizationcitations
- 2011Support-Induced Effects of LaFeO3Perovskite on the Catalytic Performances of Supported Pt Catalysts in DeNOxApplicationscitations
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article
Perfectly Transparent Sr3Al2O6 Polycrystalline Ceramic Elaborated from Glass Crystallization
Abstract
The highly visible and infrared (up to 6 mu m) transparent Sr3Al2O6 polycrystalline ceramic was obtained by full crystallization of the corresponding glass composition. The glass synthesis and the direct congruent crystallization processes are described, and the material transparency is discussed in light of its microstructure. This new transparent ceramic exhibits a high density (i.e., complete absence of porosity) and micrometer-scale crystallites with very thin grain boundaries. These microstructural characteristics, inherent to the preparation method, minimize light scattering and demonstrate the advantages of this synthesis route compared to the high-pressure process used for the few reported transparent polycrystalline materials. This Sr3Al2O6 ceramic shows a H = 10.5 GPa hardness, a E-r = 150 GPa reduced elasticity modulus, and a 9.6 x 10(-6) K-1 thermal expansion coefficient. Such a transparent strontium aluminate ceramic opens the way to a wide range of applications, especially photonics when doped by various doping agents. As examples, the luminescence of Sr3Al2O6:Eu3+ and Sr3Al2O6:Er3+, which show strong emissions in the visible and infrared ranges, respectively, is presented. Moreover, the Sr3Al2O6:Ce3+ material was found to exhibit scintillation properties under X-ray excitation. Interestingly, the analogous Sr3Ga2O6 transparent polycrystalline ceramic material could equally be prepared using the same elaboration method, although its hygroscopicity prevents the preservation of its high transparency under normal conditions. The establishment of the key factors for the transparency of this economical and innovative synthesis method should enable the prediction of new classes of technologically relevant transparent ceramics.