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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sousa, Ct
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Topics
Publications (14/14 displayed)
- 2023Tunable Iron–Cobalt Thin Films Grown by Electrodepositioncitations
- 2022Fabrication of FePt nanowires through pulsed electrodeposition into nanoporous alumina templatescitations
- 2018Activation parameters of conjugated polyaniline electrolyte via dielectric relaxation technique
- 2017Tailoring Bi-Te based nanomaterials by electrodeposition: Morphology and crystalline structurecitations
- 2015Study of magnetoelastic and magnetocrystalline anisotropies in CoxN1-x nanowire arrayscitations
- 2015Influence of sol-gel parameters in the fabrication of ferromagnetic La2/3Ca1/3MnO3 nanotube arrayscitations
- 2014Ultra-long Fe nanowires by pulsed electrodeposition with full filling of alumina templatescitations
- 2013Room Temperature Magnetic Rare-Earth Iron Garnet Thin Films with Ordered Mesoporous Structurecitations
- 2013Correlations among magnetic, electrical and magneto-transport properties of NiFe nanohole arrayscitations
- 2012pH sensitive silica nanotubes as rationally designed vehicles for NSAIDs deliverycitations
- 2012Microstructure and magnetic properties of (Fe100-xCox)(84.5)Nb5B8.5P2 alloyscitations
- 2012Influence of the Rest Pulse Duration in Pulsed Electrodeposition of Fe Nanowirescitations
- 2012Precise control of the filling stages in branched nanoporescitations
- 2011Tunning pore filling of anodic alumina templates by accurate control of the bottom barrier layer thicknesscitations
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article
Room Temperature Magnetic Rare-Earth Iron Garnet Thin Films with Ordered Mesoporous Structure
Abstract
Amphiphilic polymers are very attractive as porogens for the preparation of ordered mesoporous thin films and powders with pore sizes ranging from 40 down to a few nanometers in diameter because they are capable of both forming different superstructures and interacting with sol-gel precursors. In the present work, we report for the first time the synthesis of a series of highly crystalline rare-earth iron garnet (RE3Fe5O12, RE = Y, Gd-Dy) thin films with cubic networks of interconnected pores averaging 17 nm in diameter through facile polymer templating of hydrated nitrate salts. Despite intricate crystallization pathways, e.g., Y3Fe5O12 via Y4Fe2O9 and h-YFeO3, the nanoscale architecture of all these materials is only affected to a limited extent by solid-solid conversions at elevated temperatures. We specifically focus on the characterization of the morphology, microstructure, and magnetic properties of polymer-templated Y3Fe5O12. This novel mesoporous material is single phase after heating to 900 degrees C, free of major structural defects, and is also well-defined on the atomic level, as evidenced by a combination of in situ and ex situ scattering/diffraction techniques, electron microscopy, Raman and X-ray photoelectron spectroscopy, and time-of-flight secondary ion mass spectrometry. The high quality of the nanocrystalline Y3Fe5O12 thin films with overall soft magnetic properties and moderate anisotropy is further confirmed by SQUID magnetometry measurements. The magnetization behavior in the temperature range 5-380 K describes Bloch's T-3/2 law for a 3D Heisenberg-type ferromagnet well.