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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bahramy, Mohammad Saeed
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2022Hidden spin-orbital texture at the Γ ¯ -located valence band maximum of a transition metal dichalcogenide semiconductorcitations
- 2020Anisotropic Quantum Transport through a Single Spin Channel in the Magnetic Semiconductor EuTiO3citations
- 2020Evolution of Electronic States and Emergence of Superconductivity in the Polar Semiconductor GeTe by Doping Valence-Skipping Indiumcitations
- 2017Bulk Rashba Semiconductors and Related Quantum Phenomena.citations
- 2015Rich structural phase diagram and thermoelectric properties of layered tellurides Mo1-xNbxTe2citations
- 2012Three-dimensional bulk band dispersion in polar BiTeI with giant Rashba-type spin splittingcitations
- 2012Epitaxially Stabilized EuMoO3citations
- 2011Giant Rashba-type spin splitting in bulk BiTeIcitations
- 2008Magnetic phase stability and spin-dependent transport in ${mathrm{CeNi}}_{4}M$ ($M=mathrm{Sc}$, Ti, V, Cr, Mn, Fe, and Co)citations
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article
Epitaxially Stabilized EuMoO3
Abstract
Synthesizing metastable phases often open new functions in materials, but it is a challenging topic. Thin film techniques have advantages to form materials which do not exist in nature since nonequilibrium processes are frequently utilized. In this study, we successfully synthesize an epitaxially stabilized new compound of perovskite Eu2+Mo4+O3 as a thin film form by a pulsed laser deposition. The analogous perovskite SrMoO3 is a highly conducting paramagnetic material, but Eu2+ and Mo4+ are not compatible in equilibrium, and a previous study found that the more stable pyrochlore Eu23+Mo24+O7 prefers to form. By using isostructural perovskite substrates, the gain of the interface energy between the film and the substrate stabilizes the matastable EuMoO3 phase. This compound exhibits high conductivity and large magnetic moment, originating from Mo 4d2 electrons and Eu 4f7 electrons, respectively. Our result indicates the epitaxial stabilization is effective not only to stabilize crystallographic structures but also to form a new compound which contains unstable combinations of ionic valences in bulk form.