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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Attfield, J. Paul
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2023Doping-independent 120° magnetism in the quadruple perovskite CaMn3V4O12
- 2022Structural, magnetic, and electrical properties of Bi1-xLaxMnO3 (x=0.0, 0.1, and 0.2) solid solutionscitations
- 20221 : 1 Ca 2+ :Cu 2+ A‐site Order in a Ferrimagnetic Double Double Perovskitecitations
- 20221:1 Ca2+:Cu2+ A-site order in a ferrimagnetic double double perovskitecitations
- 2020Unconventional magnetism in the high pressure ‘all transition metal’ double perovskite Mn<sub>2</sub>NiReO<sub>6</sub>citations
- 2019Ferri- and ferro-magnetism in CaMnMReO 6 double double perovskites of late transition metals M = Co and Nicitations
- 2012Structural, magnetic, and electrical properties of Bi 1-x La x MnO 3 (x=0.0, 0.1, and 0.2) solid solutionscitations
- 2012Structural, magnetic, and electrical properties of Bi1-xLaxMnO3 (x=0.0, 0.1, and 0.2) solid solutionscitations
- 2011Metamagnetism and soliton excitations in the modulated ferromagnetic Ising chain CoV2O6citations
- 2008Subtle structural variation in copper metal-organic frameworks: Syntheses, structures, magnetic properties and catalytic behaviourcitations
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article
Structural, magnetic, and electrical properties of Bi1-xLaxMnO3 (x=0.0, 0.1, and 0.2) solid solutions
Abstract
Possible ferromagnetic and ferroelectric orders in ceramic Bi<sub>1–<i>x</i></sub>La<sub><i>x</i></sub>MnO<sub>3</sub> (<i>x</i>= 0.0, 0.1, and 0.2) samples prepared under 3–6 GPa pressure have beeninvestigated. Rietveld fits to powder neutron diffraction data show thatBiMnO<sub>3</sub> and Bi<sub>0.9</sub>La<sub>0.1</sub>MnO<sub>3</sub> adopt a monoclinic <i>C</i>2/<i>c</i> perovskite superstructure whereas Bi<sub>0.8</sub>La<sub>0.2</sub>MnO<sub>3</sub> has orthorhombic <i>Pnma</i> symmetry. Both structural analysis and Curie–Weiss fits to magnetic susceptibility data show that high spin <i>d</i><sup>4</sup> Mn<sup>3+</sup> is present with no significant Bi deficiency or Mn<sup>4+</sup> content apparent. La substitution suppresses the magnetic Curie temperature of the monoclinic phase from 105 K for <i>x</i> = 0 to 94 K at <i>x</i> = 0.1, but the <i>x</i> = 0.2 material shows antiferromagnetic order similar to that of LaMnO<sub>3</sub>. Impedance spectroscopy and dielectric measurements on the <i>x</i>= 0.1 and 0.2 materials show modest bulk permittivity values (45–80)down to 50 K, and there is no strong evidence for ferroelectricbehavior. The two samples have thermally activated conductivities withactivation energies of 0.21–0.24 eV.