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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Dalton, Larry R.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2011Systematic nanoengineering of soft matter organic electro-optic materialscitations
- 2010Definition of critical structure/function relationships and integration issues for organic electro-optic materials
- 2010Organic electro-optic materials
- 2008Guest-host cooperativity in organic materials greatly enhances the nonlinear optical responsecitations
- 2007Theory-Guided Design and Synthesis of Multichromophore Dendrimerscitations
- 2006Theoretically-inspired rational design of electro-optic materials
- 2005Systematic Study of the Structure-Property Relationship of a Series of Ferrocenyl Nonlinear Optical Chromophorescitations
- 2004Investigation of polymers and marine-derived DNA in optoelectronicscitations
- 2001Advancements in conductive cladding materials for nonlinear optic polymer based optoelectronic devicescitations
- 2000Realization of polymeric electro-optic modulators with less than one volt drive voltage requirementcitations
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article
Systematic nanoengineering of soft matter organic electro-optic materials
Abstract
An overview of the development and utilization of organic electro-optic materials is presented with emphasis on the role played by quantum and statistical mechanical calculations in understanding critical structure/function relationships that have guided the improvement of such materials over the past two decades. This review concentrates largely on three classes of organic electro-optic materials prepared by electric field poling of materials near their glass transition temperature: (1) chromophore/polymer composite materials, (2) dendrimers and polymers containing covalently incorporated chromophores, and (3) matrix-assisted-poling (MAP) materials where specific spatially anisotropic interactions enhance poling efficiency. In particular, the role of chromophore shape, restrictions on chromophore motion associated with covalent bonds, and lattice dimensionality effects are reviewed. The role of device design and auxiliary properties (optical loss, thermal stability, photochemical stability, processability) in influencing the utilization of organic electro-optic materials is also briefly reviewed. © 2010 American Chemical Society.