• Celso, F. Lo
• Imrie, Corrie
• Gordon, C. M.
• Ingram, M. D.
• Kennedy, A. R.
• Triolo, A.
• Roche, J. De

Abstract

<p>A range of analytical techniques (DSC, conductivity measurement, Raman spectroscopy, small- and wide-angle X-ray diffraction (S-WAXS), quasi-elastic neutron scattering (QENS), and single-crystal X-ray diffraction) are applied to the characterization of the phase behavior of the low-melting-point liquid crystalline salts 1-hexadecyl-3-methylimidazolium hexafluorophosphate ([C(16)mim][PF6]) and 1-methyl-3-tetradecylimidazolium hexafluorophosphate [C(14)mim][PF6]. This is the first time that QENS has been applied to the structural analysis of this type of ionic liquid crystal. For the first time in this class of salts, a low-temperature phase transition is identified, which is assigned to a crystal-crystal transition. Conductivity and QENS data for [C(16)mim] [PF6] suggest that the higher-temperature crystalline phase (C-II) has greatly increased freedom in its long alkyl chain and anion than the lower-temperature crystalline phase (C-I). This conclusion is supported by single-crystal X-ray diffraction results for [C(14)mim][PF6]. In both crystalline phases, as well as in the higher-temperature mesophase, the structure maintains a monodispersed layer structure with interdigitated alkyl chains. The structure of the mesophase is confirmed as smectic A by the S-WAXS and Raman spectroscopy results. Detailed analysis suggests that in this phase the alkyl chains undergo complete conformational melting.</p>

Topics

• impedance spectroscopy
• crystalline phase
• phase transition
• differential scanning calorimetry
• Raman spectroscopy
• liquid crystal
• wide-angle X-ray diffraction
• Elastic neutron scattering