| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Su, Bao-Lian
University of Namur
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (27/27 displayed)
- 2022Low-pressure plasma process for the dry synthesis of cactus-like Au-TiO2 nanocatalysts for toluene degradationcitations
- 2021BN‐doped metal–organic frameworks: tailoring 2D and 3D porous architectures through molecular editing of borazinescitations
- 2020UV scattering by pores in avian eggshellscitations
- 2020Scattering of ultraviolet light by avian eggshellscitations
- 2020Immobilization of a Molecular Re Complex on MOF-derived Hierarchical Porous Carbon for CO2 Electroreduction in Water/Ionic Liquid Electrolytecitations
- 2019Radiative and non radiative recombinations study in the novel nanocomposites BiVO 4 /3DOM-TiO 2 , ZnO/3DOM-TiO 2 and BiVO 4 /3DOM-ZnOcitations
- 2016ZnO quantum dots decorated 3DOM TiO2 nanocompositescitations
- 2015Single-walled metal-organic nanotube built from a simple synthoncitations
- 2015Novel 3DOM BiVO4/TiO2 nanocomposites for highly enhanced photocatalytic activitycitations
- 2015Generalized approach to the microstructure direction in metal oxide ceramics via polymerization-induced phase separationcitations
- 2015Experimental and theoretical study of optical properties and quantum size phenomena in the BiVO4/TiO2 nanostructurescitations
- 2014Synthesis of novel mesoporous ZnO/SiO2 composites for the photodegradation of organic dyescitations
- 2013A comprehensive study of the reaction parameters involved in the synthesis of Silica thin films with well-ordered uni-directional mesoporescitations
- 2012Catalytic performance of core-shell and alloy Pd-Au nanoparticles for total oxidation of VOCcitations
- 2011Whole-cell based hybrid materials for green energy production, environmental remediation and smart cell-therapycitations
- 2011Structure and surface chemistry in crystalline mesoporous (CeO -δ)-YSZcitations
- 2011(Di)-aminoguanidine functionalization through transaminationcitations
- 2011Superlative scaffold of 1,2,4-triazole derivative of glycine steering linear chain to a chiral helicatecitations
- 2011(Di)-aminoguanidine Functionalization through Transamination: An Avenue to an Auspicious Class of Supramolecular Synthonscitations
- 2011Influence of the meso-macroporous ZrO -TiO calcination temperature on the pre-reduced Pd/ZrO -TiO (1/1) performances in chlorobenzene total oxidationcitations
- 2010Engineering three-dimensional chains of porous nanoballs from a 1,2,4-triazole-carboxylate supramolecular synthoncitations
- 2010Effect of nonionic surfactants on structure, texture, and morphology of titania-doped YSZcitations
- 2009Quantum Size Effect and very localized random laser in ZnO@mesoporous silica nanocomposite following a two-photon absorption processcitations
- 2008Removal of evans blue by using nickel-iron layered double hydroxide (LDH) nanoparticlescitations
- 2007Nanosized ZnO confined inside a Faujasite X zeolite matrixcitations
- 2007Nanosized ZnO confined inside a Faujasite X zeolite matrix:Characterization and optical propertiescitations
- 2007New phenomenon in the channels of mesoporous silicate CMI-1: quantum size effect and two-photon absorption of ZnO nanoparticlescitations
Places of action
| Organizations | Location | People |
|---|
article
(Di)-aminoguanidine functionalization through transamination
Abstract
N-4H-1,2,4-Triazol-4-yl-guanidine hydrochloride (L1) and a heterocyclized 3,4-diamino-4H-1,2,4-triazole hydrochloride (L2) were synthesized in good yields thanks to a transamination reaction of aminoguanidine and diaminoguanidine hydrochlorides, whose mechanism is presented. L1 and L2 crystallize in monoclinic (P2 /a) and triclinic (P1̄) space groups, respectively. Hydrogen bonding interactions dictated by H-donor, acceptor rich ligand framework together with lattice chloride ions in L1 and L2 organize the crystal packing into a three-dimensional (3D) supramolecular network. The crystal structure of L1 is the first one for a 1,2,4-triazole ligand constructed from aminoguanidine. Both L1 and L2 that exist in monocationic form were introduced as supramolecular synthons to prepare Zn(II) complexes. Scanning electron microscopy (SEM) images on a bulk sample of [Zn(L1) Cl ]Cl ·H O (1) reveals a spontaneous aggregation of porous balls of coccolith morphology with surface decorated sickle-shaped particles of ∼100 nm thickness, whereas a powder sample of [Zn(L2) Cl ]·H O (2) shows neat rectangular blocks of ∼470 nm thickness. Colorless crystals of 2 crystallize in a monoclinic space group (C2/c). Zn(II) ions bound chloride with NH6B⋯Cl(1) = 2.495(2) Å and N⋯H type bonding (N6⋯H3C3 = 2.743(2) Å; N2⋯H7N7 = 1.989(2) Å) affording a 3D supramolecular network. The degree of pyramidality, ∑N = 38°, observed at one of the terminal amines in L2 is still retained in 2, but "flipping" of orientation of attached protons due to directional H-bonding is observed too. Porosity partitioning by mercury porosimetry measurements on 1 and 2 reveals interparticular porosities between 7 and 15 μm. N and H gas adsorption capacities of 1 and 2 were measured by BET which shows no preference for N but a low irreversible H uptake of 3 cm /g.