693.932 PEOPLE
| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Meijer, Ew Bert
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (48/48 displayed)
- 2023Photoswitchable Liquid-to-Solid Transition of Azobenzene-Decorated Polysiloxanescitations
- 2021Consequences of Chirality in Directing the Pathway of Cholesteric Helix Inversion of π-Conjugated Polymers by Lightcitations
- 2021Unraveling the Complexity of Supramolecular Copolymerization Dictated by Triazine-Benzene Interactionscitations
- 2020Long-lived charge-transfer state from B−N frustrated Lewis pairs enchained in supramolecular copolymerscitations
- 2020Tuning polymer properties of non-covalent crosslinked PDMS by varying supramolecular interaction strengthcitations
- 2019Detailed approach to investigate thermodynamically controlled supramolecular copolymerizationscitations
- 2019Detailed approach to investigate thermodynamically controlled supramolecular copolymerizations
- 2019Stereocomplexes of discrete, isotactic lactic acid oligomers conjugated with oligodimethylsiloxanescitations
- 2019Future of supramolecular copolymers unveiled by reflecting on covalent copolymerizationcitations
- 2018Supramolecular block copolymers under thermodynamic controlcitations
- 2018Supramolecular block copolymers under thermodynamic control
- 2018Fragmentation of organic ions bearing fixed multiple charges observed in MALDI MS
- 2017Making waves in a photoactive polymer filmcitations
- 2017A four-blade light-driven plastic mill based on hydrazone liquid-crystal networkscitations
- 2017Self-assembly of hydrogen-bonding gradient copolymerscitations
- 2017Self-assembly of hydrogen-bonding gradient copolymers:sequence control via tandem living radical polymerization with transesterificationcitations
- 2015The coil-to-globule transition of single-chain polymeric nanoparticles with a chiral internal secondary structurecitations
- 2015Modular synthetic platform for the construction of functional single-chain polymeric nanoparticles:from aqueous catalysis to photosensitizationcitations
- 2015Modular synthetic platform for the construction of functional single-chain polymeric nanoparticlescitations
- 2014Consequences of block sequence on the orthogonal folding of triblock copolymerscitations
- 2014The effect of pendant benzene-1,3,5-tricarboxamides in the middle block of ABA triblock copolymers : synthesis and mechanical propertiescitations
- 2014Folding triblock copolymers
- 2014Folding polymers with pendant hydrogen bonding motifs in water : the effect of polymer length and concentration on the shape and size of single-chain polymeric nanoparticles
- 2014Folding polymers with pendant hydrogen bonding motifs in water : the effect of polymer length and concentration on the shape and size of single-chain polymeric nanoparticlescitations
- 2013Sticky Supramolecular Grafts Stretch Single Polymer Chainscitations
- 2013Nanostructured supramolecular block copolymers based on polydimethylsiloxane and polylactidecitations
- 2013Orthogonal self-assembly in folding block copolymerscitations
- 2010An overview on 12-polyurethane:Synthesis, structure and crystallizationcitations
- 2009Model transient networks from strongly hydrogen-bonded polymerscitations
- 2009Metastable supramolecular polymer nanoparticles via intramolecular collapse of single polymer chainscitations
- 2009Noncovalent synthesis of protein dendrimers
- 2008Molecular weight optimum in the mesoscopic order of chiral fluorene (Co)polymer filmscitations
- 2008Polymers with multiple hydrogen-bonded end groups and their blends
- 2007Poly(caprolactone-co-oxo-crown ether)-based poly(urethane)urea for soft tissue engineering applicationscitations
- 2006Chiral alignment of OPV chromophores: explitation of the ureidophtalimide based foldamer
- 2006Oxo-crown-ethers as comonomers for tuning polyester properties
- 2006Oxo-crown-ethers as comonomers for tuning polyester propertiescitations
- 2004Guest-host chemistry with dendrimers : stable polymer assemblies by rational designcitations
- 2003Highly emissive supramolecular oligo(p-phenylene vinylene) dendrimers
- 2002Highly ordered structures of amphiphilic polythiophenes in aqueous mediacitations
- 2002A soluble equivalent of the supramolecular, quasi-one-dimensional, semiconducting Magnus' green saltcitations
- 2001Complex dynamics of hydrogen bonded self-assembling polymers
- 2001Synthesis and properties of self organising semiconducting and luminescent polymers and model compounds
- 2000A scattering electro-optical switch based on dendrimers dispersed in liquid crystals
- 2000Micro-structure-mobility correlation in self-organised, conjugated polymer field-effect transistorscitations
- 2000Off-line size-exclusion chromatographic fractionation-matrix-assisted laser desorption ionization-time-of-flight mass spectrometry for polymer characterization. Theoretical and experimental study
- 2000Host-guest chemistry of dendritic moleculescitations
- 2000Supramolecular polymerscitations
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article
Poly(caprolactone-co-oxo-crown ether)-based poly(urethane)urea for soft tissue engineering applications
Abstract
Random copolymers of e-caprolactone and 2-oxo-12-crown-4 ether, poly(CL-co-OC), were used as soft segments in the synthesis of a set of poly(urethane)urea thermoplastic elastomers. With increasing OC content, the soft segment crystallinity decreased, which influenced the mech. properties: strain induced crystn. disappeared upon the introduction of OC into poly(CL). The material therefore became weaker, however, without a redn. in strain at break. All polymers showed mech. properties that are suitable for soft tissue engineering. Degrdn. studies of poly(CL-co-OC) copolymers revealed a higher intrinsic rate of hydrolysis as compared to poly(CL). When at least two neighboring OC units were present in the soft segment, a jump in the intrinsic hydrolysis rate was obsd. From this study we deduced an ideal OC:CL ratio for the thermoplastic elastomer soft segments for soft tissue engineering applications. An in vitro degrdn. study of these poly(urethane)urea showed an increased wt. loss. Combined with the enhanced hydrophilicity and reduced crystallinity, we are confident that this will indeed lead to an increased degrdn. rate in vivo.