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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Aseyev, Vladimir O.
University of Helsinki
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Clay Composites by In Situ Polymerization of Ionic Liquid-Based Dispersions
- 2023Amphoteric nano- and microgels with acrylamide backbone for potential application in oil recoverycitations
- 2023Clay Composites by In Situ Polymerization of Ionic Liquid-Based Dispersions
- 2022Well-dispersed clay in photopolymerized poly(ionic liquid) matrixcitations
- 2022Ophthalmic drug delivery system based on the complex of gellan and ofloxacincitations
- 2021Synthesis and characterization of novel thermo- and salt-sensitive amphoteric terpolymers based on acrylamide derivativescitations
- 2020Think Beyond the Corecitations
- 2016AuNP-Polymeric Ionic Liquid Composite Multicatalytic Nanoreactors for One-Pot Cascade Reactionscitations
- 2016Water-Dispersible Silica-Polyelectrolyte Nanocomposites Prepared via Acid-Triggered Polycondensation of Silicic Acid and Directed by Polycationscitations
- 2011Polyelectrolyte Brushes Grafted from Cellulose Nanocrystals Using Cu-Mediated Surface-Initiated Controlled Radical Polymerization.citations
- 2009Sorption of silicic acid from non-saturated aqueous solution by a complex of zinc ions with poly(vinylamine)citations
- 2004Complexation of DNA with Poly(methacryl oxyethyl trimethylammonium chloride) and Its Poly(oxyethylene) Grafted Analogue.citations
Places of action
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article
Complexation of DNA with Poly(methacryl oxyethyl trimethylammonium chloride) and Its Poly(oxyethylene) Grafted Analogue.
Abstract
Intermol. complexes of genomic polydisperse DNA with synthetic polycations have been studied.Two cationic polymers have been used, a homopolymer poly(methacryl oxyethyl trimethylammonium chloride) (PMOTAC) and its analog grafted with poly(oxyethylene).The amt. of poly(oxyethylene) grafts in the copolymer was 15 mol % and Mw of the graft was 200 g/mol.Salmon DNA (sodium salt) was used.The av. mol. wt. (Mw) of DNA was 10.4 × 106 g/mol.Cond., pH, and dynamic light scattering studies were used to characterize the complexes.The size and shape of the polyelectrolyte complex particles have been studied as a function of the cation-to-anion ratio in aq. solns. of varying ionic strengths.The polyelectrolyte complexes have extremely narrow size distributions taking into account the polydispersity of the polyelectrolytes studied.The poly(oxyethylene) grafts on PMOTAC promote the formation of small colloidally stabile complex particles.Addn. of salt shifts the macroscopic phase sepn. toward lower polycation content; i.e., complexes partly phase sep. with the mixing ratios far from 1:1.Further addn. of salt to the turbid, partly phase sepd. soln. results in the dissocn. of complexes and the polycation and DNA dissolve as individual chains. [on SciFinder(R)]