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Lewicki, J. P.
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Publications (5/5 displayed)
- 2015The thermo-oxidative degradation of poly(4-methylstyrene) and its relationship to flammabilitycitations
- 2009The thermal degradation behaviour of polydimethylsiloxane/montmorillonite nanocompositescitations
- 2009Degradative thermal analysis and dielectric spectroscopy studies of aging in polysiloxane nanocomposites
- 2008The stability of polysiloxanes incorporating nano-scale physical property modifierscitations
- 2008Investigating the ageing behavior of polysiloxane nanocomposites by degradative thermal analysiscitations
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document
Degradative thermal analysis and dielectric spectroscopy studies of aging in polysiloxane nanocomposites
Abstract
<p>The characterization o f the physical and chemical changes that occur in montmorillonite/PDMS nanocomposite elastomers as they are thermally aged is reported. Broadband Dielectric Spectroscopy (BDS) was used to track changes in the physical interaction between the polymer and clay associated with increases in non-oxidative thermal stability (as determined by TGA). The evolution of volatile siloxane species from the elastomers was characterized with Thermal Volatilization Analysis (TVA). Results suggest that the improved thermal stability and the increases in polymer/clay association are a result of significant re-structuring of the polymer network.</p>