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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Rehnberg, Nicola
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024Semi-Crystalline and Amorphous Polyesters Derived from Biobased Tri-Aromatic Dicarboxylates and Containing Cleavable Acylhydrazone Units for Short-Loop Chemical Recyclingcitations
- 2024Semi-Crystalline and Amorphous Polyesters Derived from Biobased Tri-Aromatic Dicarboxylates and Containing Cleavable Acylhydrazone Units for Short-Loop Chemical Recyclingcitations
- 2024Reversibly Crosslinked Polyurethane Fibres from Sugar-Based 5-Chloromethylfurfural: Synthesis, Fibre-Spinning and Fibre-to-Fibre Recyclingcitations
- 2024Improved chemical recyclability of 2,5-furandicarboxylate polyesters enabled by acid-sensitive spirocyclic ketal unitscitations
- 2023Short-Loop Chemical Recycling via Telechelic Polymers for Biobased Polyesters with Spiroacetal Unitscitations
- 2023Carboligation of 5-(hydroxymethyl)furfural via whole-cell catalysis to form C12 furan derivatives and their use for hydrazone formationcitations
- 2021Biobased aliphatic polyesters from a spirocyclic dicarboxylate monomer derived from levulinic acidcitations
- 2021Synthesis and melt-spinning of partly bio-based thermoplastic poly(cycloacetal-urethane)s toward sustainable textilescitations
- 2019Synthesis, life cycle assessment, and polymerization of a vanillin-based spirocyclic diol toward polyesters with increased glass-transition temperaturecitations
- 2019Effect of Relative Humidity on the Viscoelasticity of Thin Organic Films Studied by Contact Thermal Noise AFMcitations
- 2019Synthesis, life cycle assessment, and polymerization of a vanillin-based spirocyclic diol toward polyesters with increased glass transition temperaturecitations
- 2018Humidity-induced phase transitions of surfactants embedded in latex coatings can drastically alter their water barrier and mechanical propertiescitations
- 2018Humidity-Induced Phase Transitions of Surfactants Embedded in Latex Coatings Can Drastically Alter Their Water Barrier and Mechanical Propertiescitations
- 2004Synthesis and Cationic Photopolymerization of New Silicon-Containing Oxetane Monomerscitations
- 2003Allyl ethers in the thiol-ene reaction
- 2003Hyperbranched Polymers in Cationic Photopolymerization of Epoxy Systemscitations
- 2002Process for manufacture of a dendritic polyether
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document
Allyl ethers in the thiol-ene reaction
Abstract
Characteristics of polyol mercaptoalkanoates, polyol allyl ethers and coatings produced thereof are reported. The viscosities of examined thiols are in the range of 110-410 mPas (23 °C) and the density of functional groups 4-8 mmol/g. The corresponding data for the studied polyol allyl ethers are 3-240 mPas (23 °C) and 7.5-13.3 mmol/g, respectively. Formulations of these components were made and photocured as thin films (100 µm wet, glass plates) using benzophenone as initiator. The coatings were characterized with respect to methyl ethyl ketone resistance (generally > 200 single rubs), pendulum hardness (typical value 140 Ks), contact angle (44-70°), glass transition temperature (-39-2 °C), and thermogravimetric infra red analysis. The latter indicated the thiol-ene coatings to be of good thermal stability (typically 4% weight loss at 300 °C).